One-pot synthesis of primary amides on bifunctional Rh(OH)x/TS-1@KCC-1 catalysts

被引：19
作者：
Peng, Honggen [1 ]
Wang, Darui [1 ]
Xu, Le [1 ]
Wu, Peng [1 ]
机构：
[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
来源：
CHINESE JOURNAL OF CATALYSIS | 2013年 / 34卷 / 11期
基金：
中国国家自然科学基金;
关键词：
TS-1; zeolite; Core-shell material; KCC-1; Primary amide; Tandem catalyst; ORDERED MESOPOROUS MATERIALS; SILICA SHELL; CORE; NANOCOMPOSITE; NANOPARTICLES; MICROSPHERES; AMMOXIMATION; NANOSPHERES; FABRICATION; ALDOXIMES;
D O I：
10.1016/S1872-2067(12)60670-6
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A new microporous/mesoporous composite with a core-shell structure, TS-1@KCC-1, was fabricated in a microemulsion system by coating flower-like mesoporous silica (KCC-1) on the crystal surface of TS-1 zeolite. The synthesis conditions and a possible formation mechanism were studied in detail for the TS-1@KCC-1 material. A suitable temperature and assembly time were found to be 373-393 K and 4 h, respectively. The shell thickness of TS-1@KCC-1 was conveniently tuned in the range 25-80 nm. Rh(OH) x species were supported on TS-1@KCC-1, giving rise to a novel bifunctional tandem catalyst Rh(OH)(x)/TS-1@KCC-1, which effectively catalyzed the one-pot synthesis of primary amides directly from aldehydes, ammonia, and hydrogen peroxide. (C) 2013, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：2057 / 2065
页数：9
相关论文
共 58 条
  • [1] Bi-phase MOR/MFI-type zeolite core-shell composite
    Bouizi, Y
    Rouleau, L
    Valtchev, VP
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 91 (1-3) : 70 - 77
  • [2] Core-shell zeolite microcomposites
    Bouizi, Y
    Diaz, I
    Rouleau, L
    Valtchev, VP
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (12) : 1955 - 1960
  • [3] Buchel G, 1998, ADV MATER, V10, P1036, DOI 10.1002/(SICI)1521-4095(199809)10:13<1036::AID-ADMA1036>3.0.CO
  • [4] 2-Z
  • [5] Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications
    Chaudhuri, Rajib Ghosh
    Paria, Santanu
    [J]. CHEMICAL REVIEWS, 2012, 112 (04) : 2373 - 2433
  • [6] Double mesoporous silica shelled spherical/ellipsoidal nanostructures: Synthesis and hydrophilic/hydrophobic anticancer drug delivery
    Chen, Yu
    Chen, Hangrong
    Ma, Ming
    Chen, Feng
    Guo, Limin
    Zhang, Lingxia
    Shi, Jianlin
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (14) : 5290 - 5298
  • [7] From microporous to mesoporous molecular sieve materials and their use in catalysis
    Corma, A
    [J]. CHEMICAL REVIEWS, 1997, 97 (06) : 2373 - 2419
  • [8] TS-1, catalytic mechanism in cyclohexanone oxime production
    Dal Pozzo, L
    Fornasari, G
    Monti, T
    [J]. CATALYSIS COMMUNICATIONS, 2002, 3 (08) : 369 - 375
  • [9] Superparamagnetic high-magnetization microspheres with an Fe3O4@SiO2 core and perpendicularly aligned mesoporous SiO2 shell for removal of microcystins
    Deng, Yonghui
    Qi, Dawei
    Deng, Chunhui
    Zhang, Xiangmin
    Zhao, Dongyuan
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (01) : 28 - +
  • [10] Fibrous Nano-Silica Supported Ruthenium (KCC-1/Ru): A Sustainable Catalyst for the Hydrogenolysis of Alkanes with Good Catalytic Activity and Lifetime
    Fihri, Aziz
    Bouhrara, Mohamed
    Patil, Umesh
    Cha, Dongkyu
    Saih, Youssef
    Polshettiwar, Vivek
    [J]. ACS CATALYSIS, 2012, 2 (07): : 1425 - 1431
123456