New heteropolyniobates based on a bicapped Keggin-type {VNb14} cluster with selective adsorption and photocatalytic properties

被引：39
作者：
Huang, Peng [1 ]
Zhou, En-Long [1 ]
Wang, Xin-Long [1 ]
Sun, Chun-Yi [1 ]
Wang, Hai-Ning [1 ]
Xing, Yan [1 ]
Shao, Kui-Zhan [1 ]
Su, Zhong-Min [1 ]
机构：
[1] NE Normal Univ, Inst Funct Mat Chem, Key Lab Polyoxometalate Sci, Minist Educ, Changchun 130024, Jilin, Peoples R China
来源：
CRYSTENGCOMM | 2014年 / 16卷 / 41期
关键词：
HYDROGEN EVOLUTION; CRYSTAL-STRUCTURE; BUILDING-BLOCKS; POLYOXONIOBATE; WATER; POLYOXOMETALATE; CATIONS; COMPLEX; ION; H-2;
D O I：
10.1039/c4ce00960f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New heteropolyniobates based on a bicapped Keggin-type {VNb14O42(NO3)(2)} (abbreviated as {VNb14}) cluster have been successfully synthesized by conventional aqueous methods. These clusters are a type of multifunctional material, which exhibit selective adsorption for methanol, ethanol and water and photocatalytic H-2 evolution activity.
引用
收藏
页码：9582 / 9585
页数：4
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