Effective α-Tosyloxylation of Ketones Using 1,1,1-Trifluoro-2-iodoethane as Catalyst

被引：0

作者：

Zhang, Bijun ^{[1
]}

Han, Liuquan ^{[1
]}

Hu, Jiantao ^{[1
]}

Yan, Jie ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Zhejiang, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2014年 / 44卷 / 22期

关键词：

1,1,1-trifluoro-2-iodoethane; alpha-tosyloxylation; Catalysis; hypervalent iodine intermediate; M-CHLOROPERBENZOIC ACID; P-TOLUENESULFONIC ACID; HYPERVALENT IODINE REAGENTS; POLYVALENT IODINE; CARBONYL-COMPOUNDS; ORGANIC-SYNTHESIS; <HYDROXY(TOSYLOXY)IODO>BENZENE; IODOBENZENE; TOSYLOXYKETONES; OXIDATIONS;

D O I：

10.1080/00397911.2014.937500

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

With 1,1,1-trifluoro-2-iodoethane as catalyst, a novel and efficient procedure has been developed for preparation of alpha-tosyloxyketones from ketones. In this protocol, 1,1,1-trifluoro-2-iodoethane is first oxidized by m-chloroperbenzoic acid to a hypervalent iodine intermediate. The in situ-generated active iodine species then reacts with ketones to afford the corresponding alpha-tosyloxyketones in good yields.

引用

页码：3264 / 3270

页数：7

共 33 条

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