Concerning the proposed structure of (+)-laurobtusol: Spectral discrepancies with synthetic, racemic Stereoisomers

被引:4
作者
Blanchfield, JT [1 ]
Chow, S [1 ]
Bernhardt, PV [1 ]
Kennard, CHL [1 ]
Kitching, A [1 ]
机构
[1] Univ Queensland, Sch Mol & Microbial Sci, Dept Chem, Brisbane, Qld 4072, Australia
关键词
D O I
10.1071/CH04047
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Laurobtusol, a minor metabolite from Laurencia obtusa, had been assigned constitution 1 and relative stereochemistry, 2. However, several stereoisomers of this novel, cyclopropane-containing system 1 have now been synthesized and spectral correspondence between the synthesized isomers and laurobtusol is lacking.
引用
收藏
页码:673 / 676
页数:4
相关论文
共 12 条