Design of a new series of chiral phosphite-olefin ligands and their application in asymmetric catalysis

被引：29
|
作者：
Yu, Yue-Na [1 ]
Xu, Ming-Hua [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 07期
基金：
中国国家自然科学基金;
关键词：
PRIMARY ALLYLIC AMINES; ARYL BORONIC ACIDS; P-ALKENE LIGANDS; ENANTIOSELECTIVE 1,2-ADDITION; ALPHA-KETOESTERS; STEERING LIGANDS; SULFUR-OLEFINS; DIENE LIGANDS; 1,4 ADDITIONS; RHODIUM;
D O I：
10.1039/c4qo00135d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel type of open-chain chiral chelating olefin bearing a simple monophosphite unit with a binaphthyl backbone was designed and synthesized, which could serve as an elegant chiral bidentate ligand in the rhodium-catalyzed asymmetric 1,2-additions of organoboron reagents to alpha-diketones and N-sulfonyl aldimines.
引用
收藏
页码：738 / 741
页数：4
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