Use of conjugated dienones in cyclialkylations: Total syntheses of arucadiol, 1,2-didehydromiltirone, (+/-)-hinokione, (+/-)-nimbidiol, sageone, and miltirone

被引：53

作者：

Majetich, G

Liu, S

Fang, J

Siesel, D

Zhang, Y

机构：

[1] Department of Chemistry, University of Georgia, Athens

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1997年 / 62卷 / 20期

关键词：

D O I：

10.1021/jo970570q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Functionalized hydrophenanthrenes can be prepared using a cyclialkylation-based strategy. These annulations are highly dependent on the directing effects of the arene substitutents and on conformational considerations. The utility of this methodology was featured in the syntheses of six diterpenoids.

引用

页码：6928 / 6951

页数：24

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