Improved Photovoltaic Properties of Polymer Solar Cells with a Phenyl Compound as an Additive

被引：1

作者：

Jeong, Seonju ^{[1
]}

Woo, Sung-Ho ^{[1
]}

Lyu, Hong-Kun ^{[1
]}

Kim, Cham ^{[1
]}

Kim, Wook Hyun ^{[1
]}

Han, Yoon Soo ^{[2
]}

机构：

[1] Daegu Gyeongbuk Inst Sci & Technol, Green Energy Res Div, Taegu 711873, South Korea

[2] Catholic Univ Daegu, Dept Adv Energy Mat Sci & Engn, Gyongsan 712702, Gyeongbuk, South Korea

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2014年 / 14卷 / 08期

关键词：

Phenyl Compound; Polymer Solar Cells; P3HT; PCBM; Additives; OPEN-CIRCUIT VOLTAGE; PERFORMANCE; EFFICIENCY; MORPHOLOGY;

D O I：

10.1166/jnn.2014.8436

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A phenyl compound with electron withdrawing substituents, 3-fluoro-4-cyanophenol (FCP), was used as an additive in polymer solar cells with a P3HT [poly(3-hexyl thiophene)]:PCBM [[6,6]-phenyl-C61-butyric acid methyl ester] blend film. Under simulated solar illumination of AM 1.5 (100 mW/cm(2)), the devices fabricated using a P3HT: PCBM (1:0.9 w:w) layer blended with 5 wt% of FCP achieved an enhanced power conversion efficiency (PCE) of 4.8% due to the improved short circuit current and fill factor, as compared to reference cells with PCE = 4.1%. UV-visible absorption spectra, X-ray measurements and carrier mobility studies revealed that FCP facilitated the ordering of the P3HT chains, resulting in higher absorbance, larger crystal size, closer packing and enhanced hole mobility.

引用

页码：5988 / 5992

页数：5

共 39 条

[1] Efficiency enhancement of polymer photovoltaic devices using thieno-thiophene based copolymers as nucleating agents for polythiophene crystallization [J].

Bechara, R. ;

Leclerc, N. ;

Leveque, P. ;

Richard, F. ;

Heiser, T. ;

Hadziioannou, G. .

APPLIED PHYSICS LETTERS, 2008, 93 (01)

[2] PARTICLE SIZE DETERMINATION FROM X-RAY LINE BROADENING [J].

BIRKS, LS ;

FRIEDMAN, H .

JOURNAL OF APPLIED PHYSICS, 1946, 17 (08) :687-691

[3]

Brabec CJ, 2003, SPRINGER SERIES MATE, V60, P159

[4] Efficient Poly(3-hexylthiophene)-Based Bulk Heterojunction Solar Cells Fabricated by an Annealing-Free Approach [J].

Chang, Yi-Ming ;

Wang, Leeyih .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (45) :17716-17720

[5] Polymer solar cells with enhanced open-circuit voltage and efficiency [J].

Chen, Hsiang-Yu ;

Hou, Jianhui ;

Zhang, Shaoqing ;

Liang, Yongye ;

Yang, Guanwen ;

Yang, Yang ;

Yu, Luping ;

Wu, Yue ;

Li, Gang .

NATURE PHOTONICS, 2009, 3 (11) :649-653

[6] Temperature dependent characteristics of poly(3 hexylthiophene)-fullerene based heterojunction organic solar cells [J].

Chirvase, D ;

Chiguvare, Z ;

Knipper, M ;

Parisi, J ;

Dyakonov, V ;

Hummelen, JC .

JOURNAL OF APPLIED PHYSICS, 2003, 93 (06) :3376-3383

[7] Morphologies of Self-Organizing Regioregular Conjugated Polymer/Fullerene Aggregates in Thin Film Solar Cells [J].

Chiu, Mao-Yuan ;

Jeng, U-Ser ;

Su, Ming-Shin ;

Wei, Kung-Hwa .

MACROMOLECULES, 2010, 43 (01) :428-432

[8] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Dennler, Gilles ;

Scharber, Markus C. ;

Brabec, Christoph J. .

ADVANCED MATERIALS, 2009, 21 (13) :1323-1338

[9] Conjugated polymer-based organic solar cells [J].

Guenes, Serap ;

Neugebauer, Helmut ;

Sariciftci, Niyazi Serdar .

CHEMICAL REVIEWS, 2007, 107 (04) :1324-1338

[10] Advanced materials and processes for polymer solar cell devices [J].

Helgesen, Martin ;

Sondergaard, Roar ;

Krebs, Frederik C. .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (01) :36-60

← 1 2 3 4 →