Landau-Zener transitions mediated by an environment: Population transfer and energy dissipation

被引:20
作者
Dodin, Amro [1 ]
Garmon, Savannah [2 ]
Simine, Lena [1 ]
Segal, Dvira [1 ]
机构
[1] Univ Toronto, Dept Chem, Chem Phys Theory Grp, Toronto, ON M5S 3H6, Canada
[2] Univ Tokyo, Inst Ind Sci, Meguro Ku, Tokyo 1538505, Japan
基金
加拿大自然科学与工程研究理事会;
关键词
BOW-TIE MODEL; LEVEL; DYNAMICS; INTERFERENCE; MOLECULES; SYSTEMS; SURFACE; STATES;
D O I
10.1063/1.4869519
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We study Landau-Zener transitions between two states with the addition of a shared discretized continuum. The continuum allows for population decay from the initial state as well as indirect transitions between the two states. The probability of nonadiabatic transition in this multichannel model preserves the standard Landau-Zener functional form except for a shift in the usual exponential factor, reflecting population transfer into the continuum. We provide an intuitive explanation for this behavior assuming individual, independent transitions between pairs of states. In contrast, the ground state survival probability at long time shows a novel, non-monotonic, functional form with an oscillatory behavior in the sweep rate at low sweep rate values. We contrast the behavior of this open-multistate model to other generalized Landau-Zener models incorporating an environment: the stochastic Landau-Zener model and the dissipative case, where energy dissipation and thermal excitations affect the adiabatic region. Finally, we present evidence that the continuum of states may act to shield the two-state Landau-Zener transition probability from the effect of noise. (c) 2014 AIP Publishing LLC.
引用
收藏
页数:10
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