Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: the relationship between activity and redox potential

被引：35
作者：
Asahi, Masafumi [1 ]
Yamazaki, Shin-ichi [1 ]
Itoh, Shinobu [2 ]
Ioroi, Tsutomu [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Res Inst Ubiquitous Energy Devices, Ikeda, Osaka 5638577, Japan
[2] Osaka Univ, Div Adv Sci & Biotechnol, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan
来源：
DALTON TRANSACTIONS | 2014年 / 43卷 / 28期
关键词：
OXYGEN REDUCTION; 4-ELECTRON REDUCTION; (2-PYRIDYL)ALKYLAMINE LIGANDS; TRIDENTATE LIGANDS; TRIPODAL LIGANDS; O-2; REDUCTION; ADDUCTS; COORDINATION; REACTIVITY; MECHANISM;
D O I：
10.1039/c4dt00606b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Cu-II/Cu-I redox properties and electrochemical O-2 reduction activity of a series of Cu-II-complexes with pyridylalkylamine ligands were investigated in a neutral buffer solution. The relationship between Cu-II/Cu-I redox properties and O-2 reduction activity was clearly demonstrated by voltammetric analyses.
引用
收藏
页码：10705 / 10709
页数：5
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