Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: the relationship between activity and redox potential

被引：37

作者：

Asahi, Masafumi ^{[1
]}

Yamazaki, Shin-ichi ^{[1
]}

Itoh, Shinobu ^{[2
]}

Ioroi, Tsutomu ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Res Inst Ubiquitous Energy Devices, Ikeda, Osaka 5638577, Japan

[2] Osaka Univ, Div Adv Sci & Biotechnol, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 28期

关键词：

OXYGEN REDUCTION; 4-ELECTRON REDUCTION; (2-PYRIDYL)ALKYLAMINE LIGANDS; TRIDENTATE LIGANDS; TRIPODAL LIGANDS; O-2; REDUCTION; ADDUCTS; COORDINATION; REACTIVITY; MECHANISM;

D O I：

10.1039/c4dt00606b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Cu-II/Cu-I redox properties and electrochemical O-2 reduction activity of a series of Cu-II-complexes with pyridylalkylamine ligands were investigated in a neutral buffer solution. The relationship between Cu-II/Cu-I redox properties and O-2 reduction activity was clearly demonstrated by voltammetric analyses.

引用

收藏

页码：10705 / 10709

页数：5

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