Exceptionally strong electronic communication through hydrogen bonds in porphyrin-C60 pairs

被引：109

作者：

Sanchez, Luis

Sierra, Maria

Martin, Nazario ^{[1
]}

Myles, Andrew. J.

Dale, Trevor J.

Rebek, Julius, Jr.

Seitz, Wolfgang

Guldi, Dirk M.

机构：

[1] Univ Complutense Madrid, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain

[2] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA

[3] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

[4] Univ Erlangen Nurnberg, Inst Phys & Theoret Chem, D-91058 Erlangen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 28期

关键词：

electron transfer; electronic coupling; fullerenes; hydrogen bond;

D O I：

10.1002/anie.200601264

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Hooking up: Self-assembly of a porphyrin amidine and fulleropyrrolidine carboxylic acid based on a two-point amidinium-carboxylate motif leads to supramolecular dyads of high stability (Ka ≈ 107 M-1 in toluene/acetonitrile (9:1)). The synergy of the hydrogen bonds and electrostatic interactions has been shown to be particularly beneficial in terms of electronic coupling between both electroactive components of the dyads. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4637 / 4641

页数：5

共 57 条

[1] [Anonymous], 1998, ANGEW CHEM
[2] [Anonymous], 2005, Angew. Chem, V117, P2982
[3] [Anonymous], 2002, ANGEW CHEM, DOI DOI 10.1002/1521-3757(20020703)114:133.0.CO
[4] 2-R
[5] Light harvesting tetrafullerene nanoarray for organic solar cells
Atienza, CM
Fernández, G
Sánchez, L
Martín, N
Dantas, IS
Wienk, MM
Janssen, RAJ
Rahman, GMA
Guldi, DM
[J]. CHEMICAL COMMUNICATIONS, 2006, (05) : 514 - 516
[6] Berger M, 1998, ANGEW CHEM INT EDIT, V37, P2694, DOI 10.1002/(SICI)1521-3773(19981016)37:19<2694::AID-ANIE2694>3.0.CO
[7] 2-Q
[8] Brabec CJ, 2001, ADV FUNCT MATER, V11, P15, DOI 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO
[9] 2-A
[10] Charge-transfer and energy-transfer processes in π-conjugated oligomers and polymers:: A molecular picture
Brédas, JL
Beljonne, D
Coropceanu, V
Cornil, J
[J]. CHEMICAL REVIEWS, 2004, 104 (11) : 4971 - 5003

← 1 2 3 4 5 6 →