Symmetry changes and domain structures at order-disorder phase transitions in (TEA)(2)BCl4 compounds (B = Zn, Cu, Hg)

被引:16
作者
SaintGregoire, P
Bordallo, HN
Mahoui, A
Lapasset, J
Moret, J
机构
[1] C.E.M.E.S, (UPR CNRS N8011), 31055 TOULOUSE cédex
[2] G.D.P.C. (URA CNRS N233), Université Montpellier 2
关键词
order-disorder phase transitions; ferroelastics; symmetry changes; domain structure;
D O I
10.1080/00150199708014093
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The discontinuous order-disorder structural instabilities occurring in TEA(2)BCl(4) with B = Zn, Cu, Hg are studied by means of X-ray diffraction, polarized light microscopy, and from the point of view of symmetry. The sequence of phases is clarified but there remains ambiguity concerning symmetry and structure of some phases. Kinetic phenomena and unexpected residual inhomogeneity are observed in paraelastic phases after passing the ferroelastic transition.
引用
收藏
页码:57 / 63
页数:7
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