Esterification of citric acid with n-butanol over zirconium sulfate supported on molecular sieves

被引：31

作者：

Yang, Hongqin ^{[1
]}

Song, Haiyan ^{[1
]}

Zhang, Han ^{[1
]}

Chen, Ping ^{[2
]}

Zhao, Zhixi ^{[2
]}

机构：

[1] Northeast Forestry Univ, Dept Chem, Coll Sci, Harbin 150040, Peoples R China

[2] Xinjiang Normal Univ, Key Lab Pollut Monitoring & Control, Urumqi 830054, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2014年 / 381卷

关键词：

Esterification; Citric acid; Tributyl citrate; Zirconium sulfate; Support; SOLVENT-FREE CONDITION; SPONTANEOUS MONOLAYER DISPERSION; EFFICIENT ESTERIFICATION; TRIBUTYL CITRATE; CARBOXYLIC-ACIDS; FATTY-ACIDS; CATALYST; ALCOHOLS; TITANIUM; CARBON;

D O I：

10.1016/j.molcata.2013.10.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solid acid catalysts consisting of zirconium sulfate (ZS) supported on a series of molecular sieves including HZSM-5, HMS and MCM-41 were prepared and used in the esterification of citric acid with n-butanol to produce tributyl citrate (TBC). Highly dispersed ZS was supported on 40 wt.% ZS/HMS or ZS/MCM-41. whereas HZSM-5 loaded more bulk ZS species. The ZS loading and type of support showed obvious effect on thermal stability, acidity and type of acid sites. In the esterification of citric acid, 40 wt.% ZS/HMS or ZS/MCM-41 exhibited higher catalytic activity than pure ZS or 40 wt.% ZS/HZSM-5. An investigation focused on ZS/HMS showed that Bronsted and Bronsted + Lewis acid sites acted as the active center for the esterification reaction. 40 wt.% ZS/HMS calcined at 180 degrees C obtained the highest conversion of citric acid and TBC yield. The reaction was found to obey an Eley-Rideal mechanism. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：54 / 60

页数：7

共 21 条

[1] Solid trichlorotitanium(IV) trifluoromethanesulfonate TiCl3(OTf) catalyzed efficient acylation of -OH and -SH:: Direct esterification of alcohols with carboxylic acids and transesterification of alcohols with esters under neat conditions [J].

Firouzabadi, Habib ;

Iranpoor, Nasser ;

Farahi, Soghra .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 289 (1-2) :61-68

[2] Calcined zirconium sulfate supported on MCM-41 silica as acid catalyst for ethanolysis of sunflower oil [J].

Jimenez-Morales, I. ;

Santamaria-Gonzalez, J. ;

Maireles-Torres, P. ;

Jimenez-Lopez, A. .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 103 (1-2) :91-98

[3] Efficient Esterification of Fatty Acids with Alcohols Catalyzed by Zr(SO4)2 • 4H2O Under Solvent-Free Condition [J].

Juan, Joon Ching ;

Zhang, Jingchang ;

Yarmo, Mohd Ambar .

CATALYSIS LETTERS, 2008, 126 (3-4) :319-324

[4] Study of catalysts comprising zirconium sulfate supported on a mesoporous molecular sieve HMS for esterification of fatty acids under solvent-free condition [J].

Juan, Joon Ching ;

Zhang, Jingchang ;

Yarmo, Mohd Ambar .

APPLIED CATALYSIS A-GENERAL, 2008, 347 (02) :133-141

[5] Structure and reactivity of silica-supported zirconium sulfate for esterification of fatty acid under solvent-free condition [J].

Juan, Joon Ching ;

Zhang, Jingchang ;

Yarmo, Mohd Ambar .

APPLIED CATALYSIS A-GENERAL, 2007, 332 (02) :209-215

[6] Zirconium sulfate supported on activated carbon as catalyst for esterification of oleic acid by n-butanol under solvent-free conditions [J].

Juan, Joon Ching ;

Zhang, Jingchang ;

Jiang, Yajie ;

Cao, Weiliang ;

Yarmo, Mohd Ambar .

CATALYSIS LETTERS, 2007, 117 (3-4) :153-158

[7] The zirconium sulfate microcrystal structure in relation to their activity in the esterification [J].

Juan, Joon Ching ;

Zhang, Jingchang ;

Jiang, Yajie ;

Cao, Weiliang ;

Yarmo, Mohd Ambar .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 272 (1-2) :91-95

[8] Supported zirconium sulfate on carbon nanotubes as water-tolerant solid acid catalyst [J].

Juan, Joon Ching ;

Jiang, Yajie ;

Meng, Xiujuan ;

Cao, Weiliang ;

Yarmo, Mohd Ambar ;

Zhang, Jingchang .

MATERIALS RESEARCH BULLETIN, 2007, 42 (07) :1278-1285

[9] Highly efficient esterification of carboxylic acids with alcohols by montmorillonite-enwrapped titanium as a heterogeneous acid catalyst [J].

Kawabata, T ;

Mizugaki, T ;

Ebitani, K ;

Kaneda, K .

TETRAHEDRON LETTERS, 2003, 44 (51) :9205-9208

[10] Plasticization of poly(lactide) with blends of tributyl citrate and low molecular weight poly(D,L-lactide)-b-poly(ethylene glycol) copolymers [J].

Lemmouchi, Yahia ;

Murariu, Marius ;

Dos Santos, Ana Margarida ;

Amass, Allan J. ;

Schacht, Etienne ;

Dubois, Philippe .

EUROPEAN POLYMER JOURNAL, 2009, 45 (10) :2839-2848

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