Self-assembling structures of long-chain phenyl glucoside influenced by the introduction of double bonds

被引:129
作者
Jung, JH
John, G
Yoshida, K
Shimizu, T
机构
[1] JST, CREST, NARC, AIST, Tsukuba, Ibaraki 3058562, Japan
[2] NARC, AIST, Tsukuba, Ibaraki 3058565, Japan
关键词
D O I
10.1021/ja020752o
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Four long-chain phenyl glucoside amphiphiles possessing a saturated or unsaturated long alkyl chain group as the self-assembling unit of a highly organized molecular architecture were synthesized. Their self-assembling properties were investigated by EF-TEM, SEM, CD, FT-IR, and XRD. Compound 2 possessing one double bond in the lipophilic portion showed twisted helical fibers, which formed a bilayered structure with a 3.59 nm period, while compound 3 showed the helical ribbons and left-handed nanotubular structures with 150-200 nm inner diameters and ca. 20 nm of wall. Very interestingly, compound 4 possessing three double bonds showed a nanotubular structure with ca. 70 nm of inner diameter through a helical ribbon, which formed a loose bilayered structure with 4.62 nm. These results indicate that self-assembling properties strongly depend on the number of cis double bonds. Copyright © 2002 American Chemical Society.
引用
收藏
页码:10674 / 10675
页数:2
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