Metal(loid)s Transport in Hydrographic Networks of Mining Basins: The Case of the La Carolina Mining District (Southeast Spain)

This study analyses the distribution of the total metal(loid)s content accumulated in the sediments of the Grande River, the most important river course that runs through the old mining district of La Carolina (Jaen, Spain), whose waters are collected in an urban supply reservoir. In total, 102 sediments samples were taken along the river, 51 in the live-bed channel and another 51 in the floodplain. The samples analysed have high metal(loid)s content, sometimes much higher than the reference levels established by European and regional legislation for soils, especially Pb, As and Ba, with average values of 5452 mg/kg, 116 mg/kg and 2622 mg/kg, respectively. The statistical analysis of the values obtained allows the distribution of the contents of the different elements along the river to be characterized and the associations and dispersion patterns in the sediments of the metal(loid)s coming from the environmental liabilities of the numerous dumpsites and tailings dams generated by mining activity to be defined. In both cases, the high metal(loid)s content identified as well as the resulting values of various environmental indices (the enrichment factor, contamination factor, geoaccumulation index, potential ecological risk index and pollution load index), confirmed that the sediment samples were moderately to highly contaminated over extensive areas of the basin studied, with the greatest intensity and extent in the floodplain sediments.