The Al-rich region of the Al-Fe-Mn alloy system

被引:36
作者
Balanetskyy, S. [1 ,2 ]
Pavlyuchkov, D. [2 ,3 ]
Velikanova, T. [2 ]
Grushko, B. [4 ]
机构
[1] Forschungszentrum Julich, IMF IFF, D-52425 Julich, Germany
[2] IN Frantsevich Inst Problems Mat Sci, Dept Phys Chem Inorgan Mat, UA-03680 Kiev 142, Ukraine
[3] Tech Univ Freiberg, Inst Mat Sci, D-09599 Freiberg, Germany
[4] Forschungszentrum Julich, PGI 5, D-52425 Julich, Germany
关键词
Transition metal alloys and compounds; Phase diagrams; CR PHASE-DIAGRAM; CRYSTAL-STRUCTURE; TRANSLATIONAL SYMMETRY; STRUCTURE REFINEMENT; QUASI-CRYSTAL; EQUILIBRIA; ALUMINUM; RANGE; PART; INTERMETALLICS;
D O I
10.1016/j.jallcom.2014.08.232
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Phase equilibria in the Al-rich region of the Al-Fe-Mn alloy system were studied at 1070, 1020, 950, 875, 800, 740, 695 and 650 degrees C. The continuous region of the bcc solid solution was estimated between the Al-Mn and Al-Fe terminals. Also the isostructural high-temperature Al-Mn and Al-Fe gamma(1)-phases (gamma-brass type structure) form continuous regions. The Al6Mn, high-temperature T-Al11Mn4 and low-temperature gamma(2) phases dissolve up to 9.0, 14.5 and 31.0 at.% Fe, respectively, while the M-Al13Fe4, Al5Fe2 and Al2Fe phases dissolve up to 15.5, 11.5 and 10.0 at.% Mn, respectively. The thermodynamically stable decagonal D-3-phase with periodicity of 1.25 nm in the specific direction and two periodic intermetallics designated phi(P6(3)/mmc; a = 0.7554, c = 0.7872 nm) and kappa (P6(3)/m; a = 1.7630, c = 1.2506 nm) were identified. An additional ternary phase of unknown structure was also revealed. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:211 / 220
页数:10
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