[CNN]-pincer nickel(II) complexes of N-heterocyclic carbene (NHC): synthesis and catalysis of the Kumada reaction of unactivated C-Cl bonds

被引：31

作者：

Sun, Yunqiang ^{[1
]}

Li, Xiaoyan ^{[1
]}

Sun, Hongjian ^{[1
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Minist Educ, Jinan 250199, Peoples R China

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 25期

关键词：

CROSS-COUPLING REACTIONS; PINCER PALLADIUM(II) COMPLEXES; NONACTIVATED ALKYL-HALIDES; GRIGNARD-REAGENTS; METAL-COMPLEXES; TAMAO-CORRIU; LIGANDS; ACTIVATION; ARYL; CCC;

D O I：

10.1039/c4dt00461b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three novel [CNN]-pincer nickel(II) complexes with NHC-amine arms were synthesized in three steps. Complex 5b was proven to be an efficient catalyst for the Kumada coupling of aryl chlorides or aryl dichlorides under mild conditions.

引用

页码：9410 / 9413

页数：4

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