Study of Plasma Electrolytic Oxidation Coatings on Aluminum Composites

被引:35
作者
Agureev, Leonid [1 ]
Savushkina, Svetlana [1 ,2 ]
Ashmarin, Artem [1 ]
Borisov, Anatoly [2 ]
Apelfeld, Andrey [2 ]
Anikin, Kirill [2 ]
Tkachenko, Nikita [3 ]
Gerasimov, Mikhail [4 ]
Shcherbakov, Aleksandr [4 ]
Ignatenko, Vasily [4 ]
Bogdashkina, Natalia [4 ]
机构
[1] Keldysh Res Ctr, Dept Nanotechnol, Moscow 125438, Russia
[2] Natl Res Univ, Moscow Aviat Inst, Moscow 121552, Russia
[3] Moscow MV Lomonosov State Univ, Skobeltsyn Inst Nucl Phys, Moscow 11999, Russia
[4] RAS, Inst Phys Chem & Electrochem, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
aluminum composites; plasma electrolytic oxidation; ceramic-like coatings; alumina; nuclear backscattering spectrometry; XRD analysis; electrochemical behavior; 6061; AL-ALLOYS; MICROARC OXIDATION; MATRIX COMPOSITES; PROTECTIVE-COATINGS; PITTING CORROSION; CERAMIC COATINGS; SURFACE; WEAR; BEHAVIOR; LAYERS;
D O I
10.3390/met8060459
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Coatings, with a thickness of up to 75 mu m, were formed by plasma electrolytic oxidation (PEO) under the alternating current electrical mode in a silicate-alkaline electrolyte on aluminum composites without additives and alloyed with copper (1-4.5%). The coatings' structure was analyzed by scanning electron microscopy, X-ray microanalysis, X-ray photoelectron spectroscopy, nuclear backscattering spectrometry, and XRD analysis. The coatings formed for 60 min were characterized by excessive aluminum content and the presence of low-temperature modifications of alumina gamma-Al2O3 and eta-Al2O3. The coatings formed for 180 min additionally contained high-temperature corundum alpha-Al2O3, and aluminum inclusions were absent. The electrochemical behavior of coated composites and uncoated ones in 3% NaCl was studied. Alloyage of aluminum composites with copper increased the corrosion current density. Plasma electrolytic oxidation reduced it several times.
引用
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页数:12
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