Structure and Fluorescence Property of 2D Interlocked Zn(II) Coordination Polymer Constructed by V-Shaped Imidazolyl Ligand

被引：0

作者：

Hu Jin-Song ^{[1
,2
]}

Zahng Xu-Jiao ^{[1
]}

Cai Xiao-Wei ^{[1
]}

Sun Lin-Xiao ^{[1
]}

Zahng Wen-Hao ^{[1
]}

Shi Jian-Jun ^{[1
]}

Zhang Xaio-Mei ^{[1
]}

Xing Hong-Long ^{[1
]}

He Jie ^{[1
]}

机构：

[1] Anhui Univ Sci & Technol, Sch Chem Engn, Huainan 232001, Anhui, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 30卷 / 03期

关键词：

coordination polymer; V-shaped ligand; photoluminescent; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; COMPLEX;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new interlocked 2D(achiral) coordination polymers {[Zn(BIDPE)(pim)]center dot(H2O)}(n) (1) was prepared under hydrothermal conditions based on V-shaped ligand 4,4'-bis (imidazol-1-yl)diphenyl ether (BIDPE) with aliphatic pimelic acid (H(2)pim). The complex was characterized by IR spectroscopy, TGA, X-ray powder and single-crystal diffraction. It crystallizes in the monoclinic system, space group P2(1)/c. The neighboring Zn(I) ions are linked by BIDPE and pim(2-) anions to form infinitely 2D(chiral) layer, two identical 2D(chiral) layers interlocked each other to give 2D(chiral) + 2D(chiral) -> 2D(chiral) sheet. The helical directions of adjacent interlocked 2D(chiral) sheets are reverse, which stacked in ABAB mode to form 2D(chiral) network. In addition, the solid-state photoluminescent property of 1 was also studied. CCDC: 933583.

引用

页码：654 / 658

页数：5

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