Recent Advances in Oxidative R1-H/R2-H Cross-Coupling with Hydrogen Evolution via Photo-/Electrochemistry

被引：630

作者：

Wang, Huamin ^{[1
]}

Gao, Xinlong ^{[1
]}

Lv, Zongchao ^{[1
]}

Abdelilah, Takfaoui ^{[1
]}

Lei, Aiwen ^{[1
,2
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, IAS, Wuhan 430072, Hubei, Peoples R China

[2] Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China

来源：

CHEMICAL REVIEWS | 2019年 / 119卷 / 12期

基金：

中国国家自然科学基金;

关键词：

ORGANOCATALYZED ANODIC-OXIDATION; VISIBLE-LIGHT PHOTOCATALYSIS; C-H FUNCTIONALIZATION; CATION-POOL METHOD; S BOND FORMATION; ELECTROCHEMICAL SYNTHESIS; ORGANIC ELECTROSYNTHESIS; RADICAL FORMATION; TERTIARY-AMINES; H-2; EVOLUTION;

D O I：

10.1021/acs.chemrev.9b00045

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photo-/electrochemical catalyzed oxidative R-1-H/R-2-H cross-coupling with hydrogen evolution has become an increasingly important issue for molecular synthesis. The dream of construction of C-C/C-X bonds from readily available C-H/X-H with release of H-2 can be facilely achieved without external chemical oxidants, providing a greener model for chemical bond formation. Given the great influence of these reactions in organic chemistry, we give a summary of the state of the art in oxidative R-1-H/R-2-H cross-coupling with hydrogen evolution via photo/electrochemistry, and we hope this review will stimulate the development of a greener synthetic strategy in the near future.

引用

页码：6769 / 6787

页数：19

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