ENDOR and ESEEM study of the radical obtained by gamma irradiation of a single crystal of ammonium tartrate

被引：18

作者：

Brustolon, M ^{[1
]}

Maniero, AL ^{[1
]}

Jovine, S ^{[1
]}

Segre, U ^{[1
]}

机构：

[1] UNIV MODENA,DIPARTIMENTO CHIM,I-41100 MODENA,ITALY

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 1996年 / 22卷 / 04期

关键词：

D O I：

10.1163/156856796X00052

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The radical obtained by gamma irradiation of a single crystal of ammonium tartrate has been identified by paramagnetic resonance spectroscopies. The proton hyperfine coupling tensors have been obtained from the angular dependence of the ENDOR transition frequencies. ESEEM spectra of the radical have been also obtained. The intensities of the ESEEM lines are related to the depth of the modulation, which has a dramatic angular dependence.

引用

页码：359 / 368

页数：10

共 9 条

[1]

Atherton N.M., 1993, Principles of electron spin resonance, Ellis Horwood

[2] MECHANISM OF SPIN TRANSFER TO BETA-PROTONS IN PI-RADICALS - ANALYSIS OF ANISOTROPIC HYPERFINE COUPLINGS [J].