Adsorption mechanisms and the effect of oxytetracycline on activated sludge

被引:101
作者
Song, Xiancai
Liu, Dongfang
Zhang, Guowei
Frigon, Matthew
Meng, Xianrong
Li, Kexun
机构
[1] Nankai Univ, Coll Environm Sci & Engn Tianjin, Tianjin 300071, Peoples R China
[2] Nankai Univ, Key Lab Pollut Proc & Environm Criteria, Key Lab Environm Remediat & Pollut Control, Minist Educ, Tianjin 300071, Peoples R China
基金
中国国家自然科学基金;
关键词
Adsorption; Metal ions; Cationic exchange; Surface complexation; HUMIC SUBSTANCES; TETRACYCLINE; SORPTION; SOIL; ANTIMICROBIALS; CU(II); CARBON; CLAYS;
D O I
10.1016/j.biortech.2013.10.055
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The adsorption mechanisms and the effect of Oxytetracycline (OTC) onto activated sludge were studied. The results show that the adsorption of Oxytetracycline (OTC) onto activated sludge was coincident with the Langmuir, Freundlich and Temkin isotherm models. The Freundlich model had the best fit which suggested that chemical adsorption mechanism was dominant. The influences including pH and metal ions on the OTC were examined. It was demonstrated that the adsorption process was highly pH-dependant, which indicate that cationic exchange mechanisms may play an important role in the adsorption process. Na+, K+, Ca2+, Mg2+ and Cd2+ ions more or less inhibited the adsorption of OTC on activated sludge while Cu2+ enhanced the adsorption ability. The phenomenon may reflect the result that a surface complexation mechanism could involved in the adsorption. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:428 / 431
页数:4
相关论文
共 18 条
[1]   Are veterinary medicines causing environmental risks? [J].
Boxall, ABA ;
Kolpin, DW ;
Halling-Sorensen, B ;
Tolls, J .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (15) :286A-294A
[2]   Modeling tetracycline antibiotic sorption to clays [J].
Figueroa, RA ;
Leonard, A ;
Mackay, AA .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (02) :476-483
[3]   Adsorption of Tetracycline and Sulfamethoxazole on Crop Residue-Derived Ashes: Implication for the Relative Importance of Black Carbon to Soil Sorption [J].
Ji, Liangliang ;
Wan, Yuqiu ;
Zheng, Shourong ;
Zhu, Dongqiang .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2011, 45 (13) :5580-5586
[4]   Mechanisms for strong adsorption of tetracycline to carbon nanotubes: A comparative study using activated carbon and graphite as adsorbents [J].
Ji, Liangliang ;
Chen, Wei ;
Duan, Lin ;
Zhu, Dongqiang .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (07) :2322-2327
[5]   Systematic study of synergistic and antagonistic effects on adsorption of tetracycline and copper onto a chitosan [J].
Kang, Jin ;
Liu, Huijuan ;
Zheng, Yu-Ming ;
Qu, Jiuhui ;
Chen, J. Paul .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 344 (01) :117-125
[6]   Biodegradation and Adsorption of Antibiotics in the Activated Sludge Process [J].
Li, Bing ;
Zhang, Tong .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2010, 44 (09) :3468-3473
[7]   Analysis of trace levels of sulfonamide and tetracycline antimicrobials, in groundwater and surface water using solid-phase extraction and liquid chromatography/mass spectrometry [J].
Lindsey, ME ;
Meyer, M ;
Thurman, EM .
ANALYTICAL CHEMISTRY, 2001, 73 (19) :4640-4646
[8]   Influence of the presence of three typical surfactants on the adsorption of nickel (II) to aerobic activated sludge [J].
Liu, Dongfang ;
Tao, Yun ;
Li, Kexun ;
Yu, Jie .
BIORESOURCE TECHNOLOGY, 2012, 126 :56-63
[9]   Oxytetracycline sorption to organic matter by metal-bridging [J].
MacKay, AA ;
Canterbury, B .
JOURNAL OF ENVIRONMENTAL QUALITY, 2005, 34 (06) :1964-1971
[10]   Occurrence of antimicrobials in the final effluents of wastewater treatment plants in Canada [J].
Miao, XS ;
Bishay, F ;
Chen, M ;
Metcalfe, CD .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (13) :3533-3541