Reactivity of [PdCl(bdtp)](BF4) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh3)](BF4)2 (bdtp=1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)

被引：5

作者：

de Leon, Antonio ^{[1
]}

Pons, Josefina ^{[1
]}

Garcia-Anton, Jordi ^{[1
]}

Solans, Xavier ^{[2
]}

Font-Bardia, Merce ^{[2
]}

Ros, Josep ^{[1
]}

机构：

[1] Univ Autonoma Barcelona, Dept Quim, Unitat Quim Inorgan, Fac Ciencies, E-08193 Barcelona, Spain

[2] Univ Barcelona, E-08028 Barcelona, Spain

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 10期

关键词：

N; S ligand; Palladium; Crystal structure; PYRAZOLE-DERIVED LIGANDS; PD-II COMPLEXES; C-13; NMR-SPECTROSCOPY; COORDINATION CHEMISTRY; CRYSTAL-STRUCTURE; PALLADIUM(II) COMPLEXES; DINUCLEAR COMPLEXES; HEMILABILE LIGANDS; PT(II) COMPLEXES; H-1;

D O I：

10.1016/j.ica.2009.04.045

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complex [PdCl(bdtp)](BF4), in presence of AgBF4 or NaBF4, reacts with pyridine (py), triphenylphosphine (PPh3), cyanide (CN ), thiocyanate (SCN ) or azide (N-3 ) ligands, leading to the formation of the following complexes: [Pd(bdtp)(py)](BF4)(2) [1](BF4)(2) , [Pd(bdtp)(PPh3)](BF4)(2) [2](BF4)(2), [Pd(CN)(bdtp)](BF4) [3](BF4), [Pd(SCN)( bdtp)](BF4) [4](BF4) and [Pd(N-3)(bdtp)](BF4) [5](BF4). These complexes were characterised by elemental analyses, mass spectrometry, conductivity measurements, infrared and NMR spectroscopies. The crystal structure of [2](BF4)(2) was determined by single-crystal X-ray diffraction methods. The metal atom is coordinated by two azine nitrogen atoms, and one sulfur atom of the thioether-pyrazole ligand and one triphenylphosphine in a distorted square-planar geometry. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：3801 / 3806

页数：6

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