Bisphosphanylhydrazides as novel chelating phosphines in transition metal chemistry - Synthetic and catalytic studies

被引：0

作者：

Katti, KV ^{[1
]}

Reddy, VS ^{[1
]}

机构：

[1] UNIV MISSOURI, RES REACTOR, COLUMBIA, MO 65203 USA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1996年 / 109卷 / 1-4期

关键词：

bisphosphanyl hydrazides; rhodium complexes; bisphosphites; catalysts;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of alkoxy- and aryloxy- functionalized bisphosphanyl hydrazides, (RO)(2)PN(Me)N(Me)P(OR)(2), is described. Interaction of these ligands with transition metals, particularly rhodium(I), has been investigated. The steric effects around P-III centers have pronounced effects on the pathway of reactions of Rh(I) precursors. For example, the reactions of these ligands with [RhCl(CO)(2)](2) leads to the formation of carbonyl free, chlorobridged dinuclear complexes when the groups are relatively smaller (e.g., CH2CF3, Ph), whereas mononuclear carbonyl-containing complexes are formed with bulky substituents (e.g., C(6)H(3)Me(2)-2,6, C6H3(OMe)(2)-2,6).

引用

页码：161 / 164

页数：4