A Facile Electrochemical Preparation of Violarite (Ni2FeS4) Nanosheets on Carbon Sheet and its Application towards Non-Enzymatic Glucose Sensing

被引:6
|
作者
Kannan, Padmanathan Karthick [1 ]
Dinesh, Bose [2 ]
An, Chang Yong [1 ]
Chung, Chan-Hwa [1 ]
机构
[1] Sungkyunkwan Univ, Sch Chem Engn, Suwon 16419, South Korea
[2] Vellore Inst Technol Univ, Sch Adv Sci, Dept Chem, Nano & Bioelectrochem Res Lab, Vellore 632014, Tamil Nadu, India
来源
CHEMISTRYSELECT | 2017年 / 2卷 / 05期
基金
新加坡国家研究基金会;
关键词
electrodeposition; glucose sensor; metal chalcogenides; non-enzymatic; violarite; TRANSITION-METAL DICHALCOGENIDES; NIS HOLLOW SPHERES; HIGH-PERFORMANCE; GRAPHENE OXIDE; ELECTRODE MATERIAL; THIN-FILM; SENSOR; HYBRID; SUPERCAPACITORS; NANOSTRUCTURES;
D O I
10.1002/slct.201601951
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple electrochemical method is reported for the preparation of Ni2FeS4 (NFS) nanosheets on carbon sheet (CS) substrate. FESEM and EDAX data confirmed the presence of nanosheet morphology with required stoichiometry. NFS modified CS is employed as an electrode material for the development of non-enzymatic glucose sensor. Impedance data showed low charge transfer resistance for NFS/CS compared to bare CS, indicated its high charge transfer capability. The developed sensor exhibited wide linear response in two different glucose concentration ranges of 10 to 1850 mu M and 2350 to 7750 mu M with the sensitivity value of 0.71 mu A mu M-1 cm(-2) and 0.14 mu A mu M-1 cm(-2). Moreover, the selectivity data demonstrated good anti-interference property of NFS/CS towards glucose in the presence of possible interfering species viz. ascorbic acid, dopamine and uric acid.
引用
收藏
页码:1967 / 1973
页数:7
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