Enhanced photovoltaic performance of CdS quantum dots sensitized highly oriented two-end-opened TiO2 nanotubes array membrane

被引:21
作者
Gao, Sheng [1 ]
Yang, Junyou [1 ]
Liu, Ming [1 ]
Yan, Hongzhou [1 ]
Li, Weixin [1 ]
Zhang, Jiaqi [1 ]
Luo, Yubo [1 ]
机构
[1] Huazhong Univ Sci & Technol, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
Titanium oxide; Two-end-opened structure; Cadmium sulfide; Power conversion efficiency; TITANIUM-OXIDE NANOTUBE; SOLAR-CELLS; HYDROGEN GENERATION; NANOROD-ARRAY; LAYER; DEPOSITION; NANOPARTICLES; EFFICIENCY; PHOTOELECTRODES; MORPHOLOGY;
D O I
10.1016/j.jpowsour.2013.11.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CdS quantum dots (QDs) sensitized highly oriented two-end-opened TiO2 nanotubes array membrane solar cells have been fabricated in this paper. The structure, morphology and composition of the photoanodes have been characterized by XRD, SEM, TEM and EDX, respectively. It shows that the flow-through structure of two-end-opened TiO2 nanotubes can absorb more CdS nanoparticles uniformly and prevent them from clogging at the nozzles of the nanotubes. The UV-Vis adsorption spectra also indicate that the CdS sensitized two-end-opened TiO2 nanotubes have high absorbance than that of the closed-ended nanotubes. The photovoltaic parameters of the QDSSC based on the two-end-opened nanotubes array membrane are as follows: PCE = 1.64%. J(sc) = 4.91 mA cm(-2), V-oc = 0.62 V and FF = 54.3%. The PCE value of 1.64% is about 3-fold enhanced in comparison with that of the QDSSC based on the closed-ended TiO2 nanotubes array membrane. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:174 / 180
页数:7
相关论文
共 47 条
[1]   Self-organized, free-standing TiO2 nanotube membrane for flow-through photocatalytic applications [J].
Albu, Sergiu P. ;
Ghicov, Andrei ;
Macak, Jan M. ;
Hahn, Robert ;
Schmuki, Patrik .
NANO LETTERS, 2007, 7 (05) :1286-1289
[2]   A Solid-State Hybrid Solar Cell Made of nc-TiO2, CdS Quantum Dots, and P3HT with 2-Amino-1-methylbenzimidazole as an interface Modifier [J].
Balis, Nikolaos ;
Dracopoulos, Vassilios ;
Stathatos, Elias ;
Boukos, Nikolaos ;
Lianos, Panagiotis .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (21) :10911-10916
[3]  
Chen Q, 2002, ADV MATER, V14, P1208, DOI 10.1002/1521-4095(20020903)14:17<1208::AID-ADMA1208>3.0.CO
[4]  
2-0
[5]   CdS quantum dots sensitized TiO2 nanorod-array-film photoelectrode on FTO substrate by electrochemical atomic layer epitaxy method [J].
Feng, Shuanglong ;
Yang, Junyou ;
Liu, Ming ;
Zhu, Hu ;
Zhang, Jiansheng ;
Li, Gen ;
Peng, Jiangying ;
Liu, Qiongzhen .
ELECTROCHIMICA ACTA, 2012, 83 :321-326
[6]   ZnO Nanoparticles-CdS Quantum Dots/N3 Dye Molecules: Dual Photosensitization [J].
Ganesh, T. ;
Mane, Rajaram S. ;
Cai, Gangeri ;
Chang, Jin-Ho ;
Han, Sung-Hwan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (18) :7666-7669
[7]   Titanium oxide nanotube arrays prepared by anodic oxidation [J].
Gong, D ;
Grimes, CA ;
Varghese, OK ;
Hu, WC ;
Singh, RS ;
Chen, Z ;
Dickey, EC .
JOURNAL OF MATERIALS RESEARCH, 2001, 16 (12) :3331-3334
[8]   CdS sensitized vertically aligned single crystal TiO2 nanorods on transparent conducting glass with improved solar cell efficiency and stability using ZnS passivation layer [J].
Hsu, Shao-Hui ;
Hung, Sung-Fu ;
Chien, Shu-Hua .
JOURNAL OF POWER SOURCES, 2013, 233 :236-243
[9]   Dendron-tethered and templated CdS quantum dots on single-walled carbon nanotubes [J].
Hwang, SH ;
Moorefield, CN ;
Wang, PS ;
Jeong, KU ;
Cheng, SZD ;
Kotta, KK ;
Newkome, GR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (23) :7505-7509
[10]   Dye-sensitized solar cells based on oriented TiO2 nanotube arrays:: Transport, trapping, and transfer of electrons [J].
Jennings, James R. ;
Ghicov, Andrei ;
Peter, Laurence M. ;
Schmuki, Patrik ;
Walker, Alison B. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (40) :13364-13372