Gold nanoparticles promote the catalytic activity of ceria for the transalkylation of propylene carbonate to dimethyl carbonate

被引:71
作者
Juarez, Raquel [1 ]
Corma, Avelino [1 ]
Garcia, Hermenegildo [1 ]
机构
[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
关键词
TRANSESTERIFICATION; OXIDATION; METHANOL; DIOXIDE; CO2;
D O I
10.1039/b902850a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of metal oxide nanoparticles with acid or basic properties exhibit low to moderate activity towards the transalkylation of propylene carbonate with methanol; deposition of gold nanoparticles on nanoparticulated ceria significantly increases the activity of this metal oxide towards transalkylation.
引用
收藏
页码:949 / 952
页数:4
相关论文
共 15 条
[11]   The chemistry of dimethyl carbonate [J].
Tundo, P ;
Selva, M .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :706-716
[12]   CaO-ZrO2 solid solution:: A highly stable catalyst for the synthesis of dimethyl carbonate from propylene carbonate and methanol [J].
Wang, H ;
Wang, MH ;
Zhao, N ;
Wei, W ;
Sun, YH .
CATALYSIS LETTERS, 2005, 105 (3-4) :253-257
[13]   Influence of preparation methods on the structure and performance of CaO-ZrO2 catalyst for the synthesis of dimethyl carbonate via transesterification [J].
Wang, Hui ;
Wang, Mouhua ;
Liu, Shuigang ;
Zhao, Ning ;
Wei, Wei ;
Sun, Yuhan .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 258 (1-2) :308-312
[14]   Effect of base strength and basicity on catalytic behavior of solid bases for synthesis of dimethyl carbonate from propylene carbonate and methanol [J].
Wei, T ;
Wang, MH ;
Wei, W ;
Sun, YH ;
Zhong, B .
FUEL PROCESSING TECHNOLOGY, 2003, 83 (1-3) :175-182
[15]   Synthesis of dimethyl carbonate by transesterification over CaO/carbon composites [J].
Wei, T ;
Wang, MH ;
Wei, W ;
Sun, YH ;
Zhong, B .
GREEN CHEMISTRY, 2003, 5 (03) :343-346