Oxygen transfer reactions from an oxaziridinium tetrafluoroborate salt to olefins

被引：64

作者：

Lusinchi, X ^{[1
]}

Hanquet, G ^{[1
]}

机构：

[1] ECOLE CHIM POLYMERES & MAT,CNRS URA 466,F-67008 STRASBOURG,FRANCE

来源：

TETRAHEDRON | 1997年 / 53卷 / 40期

关键词：

D O I：

10.1016/S0040-4020(97)00890-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxaziridinium 5 efficiently epoxidises olefins. It reacts as an electrophilic reagent and does not transfer its oxygen to deactivated double-bonds or carbonyl functions. Epoxidation of cyclic allylic acetates shows a remarkable diastereoselectivity leading to the syn isomer. We propose that the epoxidation reaction proceeds through a one-step process. (C) 1997 Elsevier Science Ltd.

引用

页码：13727 / 13738

页数：12

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