High-Temperature Spin Crossover in Complexes of Iron(II) closo-Borates with 2,6-Bis(benzimidazol-2-yl)pyridine

被引：14

作者：

Ivanova, A. D. ^{[1
]}

Lavrenova, L. G. ^{[1
,2
]}

Korotaev, E. V. ^{[1
]}

Trubina, S. V. ^{[1
]}

Sheludyakova, L. A. ^{[1
]}

Petrov, S. A. ^{[3
]}

Zhizhin, K. Yu. ^{[4
]}

Kuznetsov, N. T. ^{[4
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia

[3] Russian Acad Sci, Siberian Branch, Inst Solid State Chem, Novosibirsk 630128, Russia

[4] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2020年 / 65卷 / 11期

基金：

俄罗斯科学基金会;

关键词：

synthesis; complexes; iron(II); 2; 6-bis(benzimidazol-2-yl)pyridine; cluster boron anions; electronic; IR; and EXAFS spectroscopy; XRD; spin crossover; TRANSITION MOLECULAR MATERIALS; BORON CLUSTER ANIONS; CHEMISTRY;

D O I：

10.1134/S0036023620110078

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New iron(II) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L) and closo-borate(2-) anions-[FeL2][B10H10] . 2H(2)O and [FeL2][B12H12] . H2O-have been synthesized. The complexes have been characterized by static magnetic susceptibility measurements, electronic (diffuse reflectance spectra), IR, and EXAFS spectroscopy, and X-ray diffraction analysis. A study of the mu(eff)(T) dependence in the temperature range 80-500 K has shown that the complexes exhibit a high-temperature spin crossover (1)A(1) double left right arrow T-5(2).

引用

页码：1687 / 1694

页数：8

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