Synthesis of 1,3-Diamines Through Rhodium-Catalyzed C-H Insertion

被引：100
|
作者：
Kurokawa, Toshiki [1 ]
Kim, Mihyong [1 ]
Du Bois, J. [1 ]
机构：
[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 15期
基金：
美国国家卫生研究院;
关键词：
amination; C-H insertion; diamines; rhodium; sulfamides; AMINATION REACTIONS; EFFICIENT SYNTHESIS; BOND FORMATION; AZIRIDINATION; SULFONAMIDES; DERIVATIVES; 1,2,5-THIADIAZOLIDINE; FUNCTIONALIZATION; 1,1-DIOXIDES; DIAMINATION;
D O I：
10.1002/anie.200806192
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A grand opening: N-Boc-N-alkylsulfamides are effective substrates for the title transformation. Oxidative cyclization is highly chemoselective as well as being both stereospecific and diastereoselective. With the advent of new protocols that facilitate ring opening of the sixmembered- ring heterocyclic products, access to differentially protected 1,3-diamines has been made possible (see scheme). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2777 / 2779
页数：3
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