Hydrogen-bonding organocatalysts for ring-opening polymerization

被引：229

作者：

Thomas, Coralie ^{[1
]}

Bibal, Brigitte ^{[2
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Univ Bordeaux, UMR CNRS 5255, Inst Sci Mol, F-33405 Talence, France

来源：

GREEN CHEMISTRY | 2014年 / 16卷 / 04期

关键词：

FUNCTIONAL ALIPHATIC POLYESTERS; METAL-FREE; ORGANIC CATALYSTS; EPSILON-CAPROLACTONE; EFFICIENT SYNTHESIS; CYCLIC CARBONATES; FACILE SYNTHESIS; LACTIDE; BLOCK; GUANIDINE;

D O I：

10.1039/c3gc41806e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the ring-opening polymerization (ROP) of cyclic esters and carbonates, hydrogen-bonding organocatalysis offers an interesting alternative to metal-based and enzymatic catalysis to access biocompatible and biodegradable polymers. The design of catalysts, strategies of activation and mechanistic elucidations are highlighted. Recent developments with functionalized monomers for applications in nanomaterials and biomedicine have opened perspectives to broaden the scope of future catalytic systems. In the field of sustainable chemistry, hydrogen-bonding structures devoted to ROP have become a full-fledged class of catalysts.

引用

页码：1687 / 1699

页数：13

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