Spectroscopy and X-ray studies of {{6,6'-dimethoxy-2,2'-[ethane-1,2-diyl-bis-(nitrilomethylidyne)]diphenolato}(aqua)-dioxouranium(VI)} dehydrate

被引:1
作者
Ataol, C. Yuksektepe [1 ]
Senyuz, N. [2 ]
Bat, H. [2 ]
机构
[1] Cankiri Karatekin Univ, Fac Sci, Dept Phys, TR-18100 Ballica, Cankiri, Turkey
[2] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55139 Kurupelit, Samsun, Turkey
关键词
COMPLEXES;
D O I
10.1134/S1070328414090139
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The C18H20N2O7U center dot 2H(2)O (I) complex has been prepared and characterized by single crystal X-ray diffraction properties (CIF file CCDC no. 913243). The title compound crystallizes in the orthorhombic system, space group Pbca with a = 19.542(5), b = 9.916(5), c = 21.940(5) , V = 4252(3) (3) and Z = 8. In complex I, the U atom has a distorted pentagonal-bipyramidal geometry with a tetradentate Schiff base ligand and water molecule in the equatorial plane and oxo atoms in the axial positions. The crystal packing occurs intra-inter molecular hydrogen bonds.
引用
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页码:671 / 675
页数:5
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