Spectroscopy and X-ray studies of {{6,6'-dimethoxy-2,2'-[ethane-1,2-diyl-bis-(nitrilomethylidyne)]diphenolato}(aqua)-dioxouranium(VI)} dehydrate

被引：1

作者：

Ataol, C. Yuksektepe ^{[1
]}

Senyuz, N. ^{[2
]}

Bat, H. ^{[2
]}

机构：

[1] Cankiri Karatekin Univ, Fac Sci, Dept Phys, TR-18100 Ballica, Cankiri, Turkey

[2] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55139 Kurupelit, Samsun, Turkey

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 40卷 / 09期

关键词：

COMPLEXES;

D O I：

10.1134/S1070328414090139

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The C18H20N2O7U center dot 2H(2)O (I) complex has been prepared and characterized by single crystal X-ray diffraction properties (CIF file CCDC no. 913243). The title compound crystallizes in the orthorhombic system, space group Pbca with a = 19.542(5), b = 9.916(5), c = 21.940(5) , V = 4252(3) (3) and Z = 8. In complex I, the U atom has a distorted pentagonal-bipyramidal geometry with a tetradentate Schiff base ligand and water molecule in the equatorial plane and oxo atoms in the axial positions. The crystal packing occurs intra-inter molecular hydrogen bonds.

引用

页码：671 / 675

页数：5

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