Facile Synthesis of Z-Scheme Ag3PO4/Sulfur-Doped g-C3N4 Heterojunction Hybrids with Enhanced Visible Light Photocatalytic Performance

被引:8
作者
Bai, Jirong [1 ]
Lv, Wenhua [2 ]
Xu, Haiyang [1 ]
Chen, Gang [1 ]
Ni, Zhijiang [1 ]
Wang, Zhilei [1 ]
Qin, Hengfei [2 ]
Zheng, Zheng [1 ]
Li, Xi [1 ,3 ]
机构
[1] Fudan Univ, Dept Environm Sci & Engn, Shanghai 200433, Peoples R China
[2] Jiangsu Univ Technol, Dept Chem & Environm Engn, Changzhou 213001, Peoples R China
[3] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China
关键词
Ag3PO4; Sulfur-Doped g-C3N4; Heterojunction; Photocatalytic Performance; GRAPHITIC CARBON NITRIDE; IN-SITU SYNTHESIS; COMPOSITE PHOTOCATALYSTS; AG3PO4/G-C3N4; COMPOSITE; PHOTOGENERATED CARRIERS; CONTROLLABLE SYNTHESIS; AG3PO4; NANOPARTICLES; HYDROGEN EVOLUTION; CHARGE SEPARATION; DOPED G-C3N4;
D O I
10.1166/jnn.2019.16561
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ag3PO4/sulfur-doped g-C3N4 heterojunctions were fabricated by the means of a facile calcination and co-precipitation method. Structural characterization suggested that Ag3PO4 was successfully loaded onto sulfur-doped g-C(3)N(4. )The absorption band edges of sulfur-doped g-C3N4 were shifted to the longer wavelength in comparison with bulk g-C3N4. The Ag3PO4/sulfur-doped g-C3N4 heterojunctions manifested substantially higher visible-light photocatalytic performance as compared with Ag3PO4/bulkg-C3N4. Photoluminescence spectra suggested that the stable Ag3PO4/SGCN heterojunctions could effectively address the electron-hole recombination rate, together with remarkably enhancing the photocatalytic activity. The enhancement of, light absorption and better dispersion in Ag3PO4/sulfur-doped g-C3N4 provide more migration channels, together with posing crucial responsibility for the enhanced photocatalytic performance.
引用
收藏
页码:5736 / 5742
页数:7
相关论文
共 48 条
[41]   A novel photofunctional g-C3N4/Ag3PO4 bulk heterojunction for decolorization of Rh.B [J].
Zhang, Feng-Jun ;
Xie, Fa-Zhi ;
Zhu, Shao-Feng ;
Liu, Jin ;
Zhang, Jun ;
Mei, Sheng-Fu ;
Zhao, Wei .
CHEMICAL ENGINEERING JOURNAL, 2013, 228 :435-441
[42]   Carbon quantum dots/Ag3PO4 complex photocatalysts with enhanced photocatalytic activity and stability under visible light [J].
Zhang, Hengchao ;
Huang, Hui ;
Ming, Hai ;
Li, Haitao ;
Zhang, Lili ;
Liu, Yang ;
Kang, Zhenhui .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (21) :10501-10506
[43]   Facile and green synthesis of novel porous g-C3N4/Ag3PO4 composite with enhanced visible light photocatalysis [J].
Zhang, Jinfeng ;
Lv, Jiali ;
Dai, Kai ;
Liu, Qi ;
Liang, Changhao ;
Zhu, Guangping .
CERAMICS INTERNATIONAL, 2017, 43 (01) :1522-1529
[44]   Heterojunctions in g-C3N4/TiO2(B) nanofibres with exposed (001) plane and enhanced visible-light photoactivity [J].
Zhang, Lin ;
Jing, Dengwei ;
She, Xilin ;
Liu, Hongwei ;
Yang, Dongjiang ;
Lu, Yun ;
Li, Jian ;
Zheng, Zhanfeng ;
Guo, Liejin .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (07) :2071-2078
[45]   In-situ hydrothermal synthesis of Ag3PO4/g-C3N4 composite and their photocatalytic decomposition of NOx [J].
Zhao, Zhihuan ;
Fan, Jimin ;
Liu, Wenhui ;
Xue, Yongqiang ;
Yin, Shu .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 695 :2812-2819
[46]   Z-scheme mechanism of photogenerated carriers for hybrid photocatalyst Ag3PO4/g-C3N4 in degradation of sulfamethoxazole [J].
Zhou, Li ;
Zhang, Wei ;
Chen, Ling ;
Deng, Huiping .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 487 :410-417
[47]   Fabrication of Z-scheme Ag3PO4/MoS2 composites with enhanced photocatalytic activity and stability for organic pollutant degradation [J].
Zhu, Chaosheng ;
Zhang, Lu ;
Jiang, Bo ;
Zheng, Jingtang ;
Hu, Ping ;
Li, Sujuan ;
Wu, Mingbo ;
Wu, Wenting .
APPLIED SURFACE SCIENCE, 2016, 377 :99-108
[48]   Graphitic Carbon Nitride (g-C3N4) Nanosheets/Graphene Composites: In Situ Synthesis and Enhanced Photocatalytic Performance [J].
Zhu, Kaixing ;
Du, Yanyan ;
Liu, Jing ;
Fan, Xiaoyan ;
Duan, Zhenya ;
Song, Guanying ;
Meng, Alan ;
Li, Zhenjiang ;
Li, Qingdang .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2017, 17 (04) :2515-2519