Efficient intermolecular [2+2+2] alkyne cyclotrimerization in aqueous medium using a ruthenium(IV) precatalyst

被引：92

作者：

Cadierno, Victorio ^{[1
]}

Garcia-Garrido, Sergio E. ^{[1
]}

Gimeno, Jose ^{[1
]}

机构：

[1] Univ Oviedo, CSIC, Inst Univ Quim Organomet Enrique Moles, Dept Quim Organ & Inorgan,Unidad Asociada, E-33006 Oviedo, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 47期

关键词：

D O I：

10.1021/ja066552k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dimeric bis(allyl)-ruthenium(IV) complex [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2] (C10H16 = 2,7-dimethylocta-2,6-diene-1,8-diyl) was found to catalyze efficiently the [2 + 2 + 2] cyclization of terminal and internal alkynes in aqueous medium. Copyright © 2006 American Chemical Society.

引用

页码：15094 / 15095

页数：2

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