Structural and electronic properties of (2,2-trans)-dirhodium(II) tetrakis(N-phenylacetamidate)

被引：9
作者：
Eagle, CT
Farrar, DG [1 ]
Holder, GN
Pennington, WT
Bailey, RD
机构：
[1] Appalachian State Univ, Dept Chem, Boone, NC 28608 USA
[2] Clemson Univ, Dept Chem, Clemson, SC 29634 USA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 596卷 / 1-2期
关键词：
aromatic rings; pi-backbonding; rhodium acetate;
D O I：
10.1016/S0022-328X(99)00556-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We have synthesized and characterized the first known 2,2-trans isomer of the N-substituted dirhodium(II) tetrakisacetamidate, Rh-2(RNAc)(4), class of compounds. The bis benzonitrile adduct exhibits a unique orthogonal arrangement of the axial aromatic rings in the solid state. Structural and electronic features suggest the presence of pi-backbonding. (C) 2000 Elsevier Science S.A. All rights reserved.
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页码：90 / 94
页数：5
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