Self-ignition risk classification for coal dust layers of three coal types on a hot surface

被引:38
|
作者
Li, Bei [1 ,2 ]
Liu, Gang [1 ]
Bi, Ming-Shu [1 ]
Li, Zhen-Bao [3 ]
Han, Bing [2 ]
Shu, Chi-Min [4 ]
机构
[1] Dalian Univ Technol, Sch Chem Engn, Dalian 116024, Liaoning, Peoples R China
[2] Inspect & Res Inst Boiler & Pressure Vessel, Dalian 116000, Liaoning, Peoples R China
[3] Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China
[4] Natl Yunlin Univ Sci & Technol, Dept Safety Hlth & Environm Engn, Touliu 64002, Yunlin, Taiwan
基金
中国国家自然科学基金;
关键词
Pulverised coal; Spontaneous combustion; Dust explosion; Thermal runaway; Thermodynamic parameters; SPONTANEOUS COMBUSTION; PORE STRUCTURE; BEHAVIOR; PYROLYSIS; KINETICS; BIOMASS; ACCUMULATIONS; TEMPERATURES; PARAMETERS; OXIDATION;
D O I
10.1016/j.energy.2020.119197
中图分类号
O414.1 [热力学];
学科分类号
摘要
Pulverised coal in industrial sites and their dust can experience spontaneous combustion and self-heating, increasing the risk of fire and dust explosion. The main objective of the present study was to resolve thermal combustibility (as reflected by comprehensive combustibility index [S-n] and kinetic properties) for three types of coal (S1-BN, S2-CY, and S3-JM) through thermal analysis. The Sn values of the samples indicated a degradation in the quality of comprehensive combustibility. Apparent activation energies (E-a) at the initial stage of spontaneous coal combustion (130-300 degrees C) were decided through Achar and Coats-Redfern methods. Moreover, thermal susceptibility (minimum auto-ignition temperature [MAIT] and thermodynamic parameters) was evaluated using the hot plate method. The MAIT values for the three coal dust layers were 210, 220, and 300 degrees C. The results exhibited that heat conduction was the dominant heat transfer mode that originated the temperature distribution within the coal dust layer under the subcritical conditions for ignition; while it converted chemical reaction controlled-mode after thermal runaway. Furthermore, the results based on an improved risk matrix approach showed the S1-BN and S2-CY samples had a high self-ignition risk, whereas the S3-JM sample had a moderate ignition risk. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页数:14
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