NaAlH4 production from waste aluminum by reactive ball milling

被引：8

作者：

Bergemann, Nils ^{[1
]}

Pistidda, Claudio ^{[1
]}

Milanese, Chiara ^{[2
,3
]}

Girella, Alessandro ^{[2
,3
]}

Hansen, Bjarne R. S. ^{[4
,5
]}

Wurr, Johannes ^{[1
]}

von Colbe, Jose M. Bellosta ^{[1
]}

Jepsen, Julian ^{[1
]}

Jensen, Torben R. ^{[4
,5
]}

Marini, Amedeo ^{[2
,3
]}

Klassen, Thomas ^{[1
]}

Dornheim, Martin ^{[1
]}

机构：

[1] Helmholtz Zentrum Geesthacht, Inst Mat Res, D-21502 Geesthacht, Germany

[2] Univ Pavia, CSGI, Pavia Lab H2, I-27100 Pavia, Italy

[3] Univ Pavia, Dipartimento Chim, Sez Chim Fis, I-27100 Pavia, Italy

[4] Aarhus Univ, iNANO, Ctr Mat Crystallog, DK-8000 Aarhus, Denmark

[5] Aarhus Univ, Dept Chem, DK-8000 Aarhus, Denmark

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2014年 / 39卷 / 18期

关键词：

Hydrogen storage; Mechanochemical synthesis; DTA; PXD; In situ SRPXD; Sodium alanate; LIGHT-METAL HYDRIDES; HYDROGEN-STORAGE; SYSTEM;

D O I：

10.1016/j.ijhydene.2014.02.025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Due to its thermodynamic properties and high reversibility, Ti doped sodium alanate is considered as a prototype hydrogen storage material. In this work we show how sodium alanate can be synthesized by reactive ball milling using aluminum particles obtained from recycled waste incineration slag. The synthesis was monitored with an in situ milling vial and characterized stepwise by PXD and DTA analyses. The sorption properties of the material were investigated using in situ synchrotron radiation PXD and volumetric analyses. A complete conversion of the starting reactants was obtained. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：9877 / 9882

页数：6

共 22 条

[1] DIRECT SYNTHESIS OF COMPLEX METAL HYDRIDES [J].

ASHBY, EC ;

REDMAN, HE ;

BRENDEL, GJ .

INORGANIC CHEMISTRY, 1963, 2 (03) :499-&

[2] One-step direct synthesis of a Ti-doped sodium alanate hydrogen storage material [J].

Bellosta von Colbe, JM ;

Felderhoff, M ;

Bogdanovic, B ;

Schüth, F ;

Weidenthaler, C .

CHEMICAL COMMUNICATIONS, 2005, (37) :4732-4734

[3] Hydrogen sorption properties of MgH2-LiBH4 composites [J].

Boesenberg, Ulrike ;

Doppiu, Stefania ;

Mosegaard, Lene ;

Barkhordarian, Gagik ;

Eigen, Nico ;

Borgschulte, Andreas ;

Jensen, Torbert R. ;

Cerenius, Yngve ;

Gutfleisch, Oliver ;

Klassen, Thomas ;

Dornheim, Martin ;

Bormann, Ruediger .

ACTA MATERIALIA, 2007, 55 (11) :3951-3958

[4] Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials [J].

Bogdanovic, B ;

Schwickardi, M .

JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 253 (1-2) :1-9

[5] MECHANICAL ALLOYING OF THE FE-ZR SYSTEM - CORRELATION BETWEEN INPUT ENERGY AND END-PRODUCTS [J].

BURGIO, N ;

IASONNA, A ;

MAGINI, M ;

MARTELLI, S ;

PADELLA, F .

NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS, 1991, 13 (04) :459-476

[6] INSITU CELL FOR COMBINED XRD AND ONLINE CATALYSIS TESTS - STUDIES OF CU-BASED WATER GAS SHIFT AND METHANOL CATALYSTS [J].

CLAUSEN, BS ;

STEFFENSEN, G ;

FABIUS, B ;

VILLADSEN, J ;

FEIDENHANSL, R ;

TOPSOE, H .

JOURNAL OF CATALYSIS, 1991, 132 (02) :524-535

[7] In situ pressure and temperature monitoring during the conversion of Mg into MgH2 by high-pressure reactive ball milling [J].

Doppiu, S. ;

Schultz, L. ;

Gutfleisch, O. .

JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 427 (1-2) :204-208

[8]

DYMOVA TN, 1974, DOKL AKAD NAUK SSSR+, V215, P1369

[9] Industrial production of light metal hydrides for hydrogen storage [J].

Eigen, Nico ;

Keller, Claude ;

Dornheim, Martin ;

Klassen, Thomas ;

Bormann, Ruediger .

SCRIPTA MATERIALIA, 2007, 56 (10) :847-851

[10] Versatile in situ powder X-ray diffraction cells for solid-gas investigations [J].

Jensen, Torben R. ;

Nielsen, Thomas K. ;

Filinchuk, Yaroslav ;

Jorgensen, Jens-Erik ;

Cerenius, Yngve ;

Gray, Evan MacA ;

Webb, Colin J. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 :1456-1463

← 1 2 3 →