Efficient, stable, and reusable Lewis acid-surfactant-combined catalyst: One-pot Biginelli and solvent-free esterification reactions

被引：29

作者：

Qiu, Yunfeng ^{[1
,2
]}

Sun, Hongnan ^{[1
,2
]}

Ma, Zhuo ^{[3
]}

Xia, Wujiong ^{[1
,2
]}

机构：

[1] Harbin Inst Technol, SKLUWRE, Harbin 150080, Heilongjiang, Peoples R China

[2] Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, Harbin 150080, Heilongjiang, Peoples R China

[3] Harbin Inst Technol, Sch Life Sci & Technol, Harbin 150080, Heilongjiang, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2014年 / 392卷

基金：

中国博士后科学基金;

关键词：

Lewis acid-surfactant combined catalyst; Biginelli; Esterification; Micro reactor; Solvent-free; SODIUM DODECYL-SULFATE; CARBOXYLIC-ACIDS; GREEN CHEMISTRY; DIHYDROPYRIMIDINE SYNTHESIS; ALDOL REACTIONS; WATER; 1,4-DIHYDROPYRIDINES; POLYCONDENSATION; NANOPARTICLES; ALLYLATION;

D O I：

10.1016/j.molcata.2014.04.031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cerium(III)trislaurylsulfonate (Ce(LS)(3)), a Lewis acid and surfactant combined catalyst, was prepared and characterized by SEM, SEM-EDX, XRD, NMR, FT-IR, TG, and elemental analysis. Ce(LS)(3) was found to be stable and efficient to catalyze one-pot Biginelli and solvent-free esterification reactions. Furthermore, Ce(LS)(3) is easy to recycle after reaction by pouring into cold water and filtration. Present work will shed deep insight into the understanding of the catalytic nature of LASCs, and extend its application in important organic transformations. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：76 / 82

页数：7

共 59 条

[1] Iron(III) trifluoro acetate and trifluoromethanesulfonate: Recyclable Lewis acid catalysts for one-pot synthesis of 3,4-dihydropyrimidinones or their sulfur analogues and 1,4-dihydropyridines via solvent-free Biginelli and Hantzsch condensation protocols [J].

Adibi, Hadi ;

Samimi, Heshmat Allah ;

Beygzadch, Mojtaba .

CATALYSIS COMMUNICATIONS, 2007, 8 (12) :2119-2124

[2] THE THERMAL-BEHAVIOR OF BASIC LEAD(II) DODECYL-SULFATE [J].

AKANNI, MS ;

BURROWS, HD ;

ELLIS, HA ;

OZOWARA, IE .

THERMOCHIMICA ACTA, 1982, 59 (01) :19-23

[3]

Amarante FWO, 2008, STUD SURF SCI CATAL, V174, P1303

[4] Green Chemistry: Principles and Practice [J].

Anastas, Paul ;

Eghbali, Nicolas .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :301-312

[5] Nanoparticles as recyclable catalysts: The frontier between homogeneous and heterogeneous catalysis [J].

Astruc, D ;

Lu, F ;

Aranzaes, JR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (48) :7852-7872

[6]

ATWAL KS, 1987, HETEROCYCLES, V26, P1189

[7] SIMPLE AND REGIOSELECTIVE SYNTHESIS OF N-SUBSTITUTED PYRIMIDINE-2(1H)-ONES AND PYRIMIDINE-2(1H)-THIONES [J].

BARLUENGA, J ;

TOMAS, M ;

RUBIO, V ;

GOTOR, V .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (16) :675-676

[8] Polyester synthesis in aqueous miniemulsion [J].

Barrère, M ;

Landfester, K .

POLYMER, 2003, 44 (10) :2833-2841

[9] A revision of the Biginelli reaction under solid acid catalysis. Solvent-free synthesis of dihydropyrimidines over montmorillonite KSF [J].

Bigi, F ;

Carloni, S ;

Frullanti, B ;

Maggi, R ;

Sartori, G .

TETRAHEDRON LETTERS, 1999, 40 (17) :3465-3468

[10]

Biginelli P., 1893, GAZZ CHIM ITAL, V23, P360

← 1 2 3 4 5 6 →