Reaction of five-membered zirconacycloallenoids with the strong Lewis acid B(C6F5)3

被引：5

作者：

Bender, Georg ^{[1
]}

Daniliuc, Constantin G. ^{[1
]}

Wibbeling, Birgit ^{[1
]}

Kehr, Gerald ^{[1
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 32期

关键词：

ZIEGLER CATALYST SYSTEMS; CENTER-DOT F; OLEFIN POLYMERIZATION; COMPLEXES; TRIS(PENTAFLUOROPHENYL)BORANE; METALLACYCLES; ALKYNES;

D O I：

10.1039/c4dt01137f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two alkyl and aryl substituted five-membered zirconacycloallenoids underwent a typical metallocene reaction with B(C6F6)(3), namely cleavage of the Zr-C(sp(3)) bond with formation of zwitterionic (eta(2)-allenyOzirconium/alkylborate products. Both products were characterized by X-ray crystal structural analyses.

引用

页码：12210 / 12213

页数：4

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