Construction of a functional layered solid using the tetrakis(imidazolyl)borate coordinating anion

被引：31
作者：
Hamilton, BH [1 ]
Kelly, KA [1 ]
Wagler, TA [1 ]
Espe, MP [1 ]
Ziegler, CJ [1 ]
机构：
[1] Univ Akron, Dept Chem, Knight Chem Lab, Akron, OH 44325 USA
来源：
INORGANIC CHEMISTRY | 2002年 / 41卷 / 20期
关键词：
D O I：
10.1021/ic025796c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The coordination polymer Pb[B(Im)(4)](NO3), constructed by using tetrakis(imidazolyl)borate and lead(II) nitrate solutions, is a layered material with the metal centers facing the interlayer spacing. As occurring layered minerals, this compound can readily undergo anion exchange in the solid state with retention of crystallinity. We examined stoichiometric exchange of N-15-nitrate for nitrate and iodine for nitrate by N-15 and Pb-207 SSNMR and confirmed retention of crystallinity by IR and powder XRD diffraction.
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页码：4984 / 4986
页数：3
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