Unusual adsorption mechanism for carboxylic acid gases by polyamine-intercalated α-zirconium phosphate

被引：25
作者：
Nakayama, H [1 ]
Hayashi, A
Eguchi, T
Nakamura, N
Tsuhako, M
机构：
[1] Kobe Pharmaceut Univ, Dept Funct Mol Chem, Kobe, Hyogo 6588558, Japan
[2] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2002年 / 12卷 / 10期
关键词：
D O I：
10.1039/b201295m
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The adsorption mechanism of gaseous carboxylic acid by diethylenetriamine- or pentaethylenehexamine-intercalated alpha-zirconium phosphate was examined in detail using XRD and solid-state C-13 and P-31 NMR. The adsorption of acetic acid, propanoic acid, and butyric acid resulted in the co-intercalation of the carboxylic acid molecules into polyamine-intercalated alpha-zirconium phosphate to expand their interlayer distance by 0.64-0.97 nm. In the case of formic acid, its adsorption induced the rearrangement of the polyamine molecules within the interlayer space.
引用
收藏
页码：3093 / 3099
页数：7
相关论文
共 18 条
  • [1] SOLID-STATE NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPIC STUDY OF GAMMA-ZIRCONIUM PHOSPHATE
    CLAYDEN, NJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (08): : 1877 - 1881
  • [2] NEW CRYSTALLINE PHASES OF ZIRCONIUM PHOSPHATE POSSESSING ION-EXCHANGE PROPERTIES
    CLEARFIELD, A
    BLESSING, RH
    STYNES, JA
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1968, 30 (08): : 2249 - +
  • [3] THE PREPARATION OF CRYSTALLINE ZIRCONIUM PHOSPHATE AND SOME OBSERVATIONS ON ITS ION EXCHANGE BEHAVIOUR
    CLEARFIELD, A
    STYNES, JA
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1964, 26 (01): : 117 - 129
  • [4] Clearfield A., 1996, COMPREHENSIVE SUPRAM, V7, P107
  • [5] Intercalation of methylene blue into layered phosphates in the presence of butylamine and function of alkylamine in the intercalation reaction
    Danjo, M
    Tsuhako, M
    Nakayama, H
    Eguchi, T
    Nakamura, N
    Yamaguchi, S
    Nariai, H
    Motookata, I
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (05) : 1053 - 1060
  • [6] Structure and organic gas-adsorption properties of some polyamine intercalated α-zirconium phosphates
    Danjo, M
    Hayashi, A
    Nakayama, H
    Kimira, Y
    Shimizu, T
    Mizuguchi, Y
    Yagita, Y
    Tsuhako, M
    Nariai, H
    Motooka, I
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1999, 72 (09) : 2079 - 2084
  • [7] PYRENE SORPTION IN ORGANIC LAYERED DOUBLE-METAL HYDROXIDES
    DUTTA, PK
    ROBINS, DS
    [J]. LANGMUIR, 1994, 10 (06) : 1851 - 1856
  • [8] Intercalation of α,ω-alkanediamines in layered aluminium dihydrogen triphosphate dihydrate
    Hayashi, A
    Nakayama, H
    Tsuhako, M
    Eguchi, T
    Nakamura, N
    [J]. JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 1999, 34 (04) : 401 - 412
  • [9] Hayashi A, 2000, MOL CRYST LIQ CRYST, V341, P1377
  • [10] An acentric arrangement of p-nitroaniline molecules between the layers of kaolinite
    Kuroda, K
    Hiraguri, K
    Komori, Y
    Sugahara, Y
    Mouri, H
    Uesu, Y
    [J]. CHEMICAL COMMUNICATIONS, 1999, (22) : 2253 - 2254
12