ELIMINATION OF DYES FROM AQUEOUS SOLUTIONS USING IRON OXIDES AND CHITOSAN AS ADSORBENTS. A COMPARATIVE STUDY

被引:42
作者
Pirillo, Silvina [1 ]
Pedroni, Viviana [1 ]
Rueda, Elsa [1 ]
Lujan Ferreira, Maria [2 ]
机构
[1] Univ Nacl Sur, Dept Quim, RA-8000 Bahia Blanca, Buenos Aires, Argentina
[2] Univ Nacl Sur, CONICET, RA-8000 Bahia Blanca, Buenos Aires, Argentina
来源
QUIMICA NOVA | 2009年 / 32卷 / 05期
关键词
dyes; iron oxides; chitosan; XANTHENE DYES; ACTIVATED CARBON; ACID-SOLUTIONS; ANIONIC DYES; WASTE-WATER; ADSORPTION; KINETICS; REMOVAL; METAL; EQUILIBRIUM;
D O I
10.1590/S0100-40422009000500030
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This work investigates the adsorption of Alizarin, Eriochrome Blue Black R and Fluorescein using chitosan, goethite and magnetite as adsorbents. For Alizarin, the best adsorbent is chitosan with a Langmuir parameter of 15.8 mmol dye/g adsorbent. For Eriochrome Blue Black R only 1.94 mmol dye/g chitosan is adsorbed. Langmuir parameters for the Alizarin adsorption on both iron oxides display one or two orders of magnitude lower than for chitosan and two orders of magnitude lower in the case of Eriochrome Blue Black R. Fluorescein does not adsorb in appreciable amounts on chitosan and it presents the lower affinity on the iron oxides.
引用
收藏
页码:1239 / U176
页数:9
相关论文
共 44 条
[1]  
ALLEN DJ, 2005, J U CHEM TECHNOL MET, V40, P175
[2]   THE ADSORPTION OF ACID DYE ONTO PEAT FROM AQUEOUS-SOLUTION SOLID DIFFUSION-MODEL [J].
ALLEN, SJ ;
MCKAY, G ;
KHADER, KYH .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1988, 126 (02) :517-524
[3]   DIMERIC AND TRIMERIC STATES OF THE FLUORESCEIN DIANION .1. MOLECULAR-STRUCTURES [J].
ARBELOA, IL .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1981, 77 :1725-1733
[4]   CRYSTAL NUCLEATION IN FE(3) SOLUTIONS AND HYDRXIDE GELS [J].
ATKINSON, RJ ;
POSNER, AM ;
QUIRK, JP .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1968, 30 (09) :2371-+
[5]   Adsorption of anionic dyes on chitosan beads. 1. The influence of the chemical structures of dyes and temperature on the adsorption kinetics [J].
Cestari, AR ;
Vieira, EFS ;
dos Santos, AGP ;
Mota, JA ;
de Almeida, VP .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 280 (02) :380-386
[6]   Equilibrium and kinetic studies on the adsorption of surfactant, organic acids and dyes from water onto natural biopolymers [J].
Chang, MY ;
Juang, RS .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2005, 269 (1-3) :35-46
[7]   Intraparticle diffusion processes during acid dye adsorption onto chitosan [J].
Cheung, W. H. ;
Szeto, Y. S. ;
McKay, G. .
BIORESOURCE TECHNOLOGY, 2007, 98 (15) :2897-2904
[8]  
Chiou MS, 2003, J CHIN INST CHEM ENG, V34, P625
[9]   Adsorption of anionic dyes in acid solutions using chemically cross-linked chitosan beads [J].
Chiou, MS ;
Ho, PY ;
Li, HY .
DYES AND PIGMENTS, 2004, 60 (01) :69-84
[10]  
Cooper S.G., 1978, TEXTILE IND ENV CONT