n=2 Member of the hexagonal perovskite-intergrowth manganate family An+1 MnnO3n+3(Ca2O)

被引：8

作者：

Bie, LJ

Lin, JH ^{[1
]}

Wang, YX

Loong, CK

机构：

[1] Beijing Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

[2] Argonne Natl Lab, Div Intense Pulsed Neutron Source, Argonne, IL 60439 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 11期

基金：

中国国家自然科学基金;

关键词：

hexagonal-perovskite intergrowth manganate; solid state;

D O I：

10.1016/S1387-7003(02)00619-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The n = 2 member in hexagonal perovskite manganate family A(n+1)Mn(n)O(3n+3)(Ca2O) was obtained in a complex composition La2Ba0.8Sr0.6Ca1.6Mn2O10, but simple hexagonal structure. It crystallizes in the hexagonal P6(3)/mmc space group [a = 5.63591(5) Angstrom, c = 16.2843(3) Angstrom, V = 447.948(9) Angstrom(3); Z = 2] and consists of double hexagonal perovskite layers (2H-type) and graphite-like [Ca2O] layer. The manganese octahedra share faces resulting in localized magnetic property. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：966 / 970

页数：5

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