Activated carbon derived from chitin aerogels: preparation and CO2 adsorption

被引:46
作者
Dassanayake, Rohan S. [1 ]
Gunathilake, Chamila [2 ,3 ]
Abidi, Noureddine [1 ]
Jaroniec, Mietek [2 ]
机构
[1] Texas Tech Univ, Dept Plant & Soil Sci, Fiber & Biopolymer Res Inst, Lubbock, TX 79403 USA
[2] Kent State Univ, Dept Chem & Biochem, Kent, OH 44242 USA
[3] Univ Peradeniya, Dept Chem & Proc Engn, Fac Engn, Peradeniya 20400, Sri Lanka
关键词
Biopolymers; Chitin; CO2; capture; Aerogels; Activated carbon; SURFACE ENERGETICAL HETEROGENEITY; FUNCTIONALIZED MESOPOROUS SILICA; POROUS ORGANIC POLYMERS; BIOMEDICAL APPLICATIONS; DIOXIDE SORPTION; CHITOSAN; CAPTURE; EXTRACTION; CHITOOLIGOSACCHARIDES; TECHNOLOGIES;
D O I
10.1007/s10570-018-1660-3
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Activated carbon was prepared by carbonization and KOH activation of chitin aerogels. The resulting carbon featured high CO2 adsorption of 5.02 mmol/g at 0 A degrees C and 3.44 mmol/g at 25 A degrees C under ambient pressure of 1 atm. The activated carbon showed a high specific surface area of similar to 520 m(2)/g, total pore volume of 0.30 cm(3)/g, and volume of micropores of similar to 0.19 cm(3)/g. KOH activation of carbonized chitin aerogels resulted in about 37-fold increase in the specific surface area and about 95-fold increase in the volume of micropores as compared to the as-synthesized chitin aerogel. These data indicate that the chitin-derived activated carbon can be used for adsorption-based environmental and related applications.
引用
收藏
页码:1911 / 1920
页数:10
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