Synthesis of three d10 compounds based on N-(3-pyridylmethyl) benzimidazole, the effect of radius of metal ions on structure and the function of ligand

被引:15
|
作者
Huang, Meihua
Liu, Ping [1 ]
Chen, Yun
Wang, Jian
Liu, Zheng
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian 350002, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
group; 12; compounds; Pi interactions; ionic radius;
D O I
10.1016/j.molstruc.2005.12.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Zn2+, Cd2+ and Hg2+ complexes of L [L = N-(3-pyridylmethyl)benzimidazole] have been synthesized and characterized by single crystal X-ray analysis and fluorescence spectra as well as TGA analysis. The Zn2+ compound is monomeric, the Cd2+ complex is of double-bridge chain, while the Hg2+ complex is of wave-like chain. These compounds reveal the metal radius interaction on structural types and the function of ligand. (c) 2006 Published by Elsevier B.V.
引用
收藏
页码:211 / 217
页数:7
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