A novel organic-inorganic hybrid compound based on Anderson-type polyoxometalates and anthranilamide

被引：1

作者：

Thabet, Safa ^{[1
]}

Ayed, Brahim ^{[1
]}

Haddad, Amor ^{[1
]}

机构：

[1] Fac Sci, Dept Chim, Lab Mat & Cristallochim, Monastir 5000, Tunisia

来源：

COMPTES RENDUS CHIMIE | 2015年 / 18卷 / 09期

关键词：

Hybrids material; Polyoxometalates; Anderson-B anion; X-ray diffraction; Photoluminescent property; CRYSTAL-STRUCTURE; BUILDING-BLOCKS; CHAIN; HETEROPOLYMOLYBDATE; POLYOXOANIONS; POLYANIONS; ANIONS;

D O I：

10.1016/j.crci.2015.06.020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new organic-inorganic hybrid material, (C7H9N2O)(2)[Al(OH)(7)Mo6O17]center dot 12H(2)O (1), was prepared and characterized by elemental analysis, IR and UV-visible spectroscopies, TG-DTA analysis, and single-crystal X-ray diffraction. The title compound crystallizes in the triclinic system, space group P (1) over bar with a= 10.237(2) angstrom, b = 10.415(1) angstrom, c= 10.545(1) angstrom, alpha= 87.27(1)degrees, beta = 102.17(1)degrees, gamma = 95.24(1)degrees, Z=1. Single-crystal X-ray analysis shows that compound (1) possesses a 3D framework, which is built up of Anderson polyoxoanions, organic cations and water molecules; the extensive net hydrogen bonds between cations and anions contribute to the crystal packing. Furthermore, the luminescent property of (1) in the solid state was investigated. (C) 2015 Published by Elsevier Masson SAS on behalf of Academie des sciences.

引用

页码：979 / 985

页数：7

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