Direct and Indirect Electro-Oxidative Intramolecular C-H Aminations

被引：9
|
作者：
Wang, Huiqiao [1 ]
Xu, Kun [2 ]
机构：
[1] Anyang Inst Technol, Sch Chem & Environm Engn, Anyang 455099, Peoples R China
[2] Beijing Univ Technol, Fac Environm & Life, Beijing 100124, Peoples R China
来源：
TRANSACTIONS OF TIANJIN UNIVERSITY | 2022年 / 28卷 / 06期
关键词：
Electrosynthesis C-H amination N-heterocycle Indirect electrolysis; ELECTROCHEMICAL SYNTHESIS;
D O I：
10.1007/s12209-022-00342-x
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The ubiquity of N-heterocycles in marketed drugs makes the development of metal-free methodologies for constructing C-N bonds of considerable importance. As an environmentally friendly method, electro-oxidative intramolecular C-H amination has emerged as a powerful platform for synthesizing nitrogen-containing heterocycles under metal- and external oxidant-free conditions. In this minireview, the main achievements in this direction since 2020 are summarized, with an emphasis on the substrate scope and mechanistic aspects. The reactions are classified into two categories: direct and indirect electro-oxidative intramolecular C-H aminations.
引用
收藏
页码：469 / 481
页数：13
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