A simple and eco-sustainable method for the sulfonylation of amines under microwave-assisted solvent-free conditions

被引：27

作者：

Lakrout, Salah ^{[1
]}

K'tir, Hacene ^{[1
]}

Amira, Aicha ^{[1
]}

Berredjem, Malika ^{[1
]}

Aouf, Nour-Eddine ^{[1
]}

机构：

[1] Badji Mokhtar Annaba Univ, Dept Chem, Fac Sci, Lab Appl Organ Chem,Bioorgan Chem Grp, Annaba 23000, Algeria

来源：

RSC ADVANCES | 2014年 / 4卷 / 31期

关键词：

DEPROTECTION; PROTECTION; ANTICANCER; INHIBITORS; CATALYST; OVENS; OXIDE; MILD;

D O I：

10.1039/c4ra01346h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new environmentally benign, simple, and efficient protocol for the chemoselective sulfonylation of various structural amines using microwave irradiation under solvent-and catalyst-free conditions is reported. The corresponding sulfonamides were obtained in excellent yields within short reaction times. Simplicity, milder, cleaner and greener conditions, easier work-up, and lower generation of waste or pollution are the main advantages of this method.

引用

页码：16027 / 16032

页数：6

共 30 条

[1] Deprotection of sulfonyl aziridines [J].

Alonso, DA ;

Andersson, PG .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (25) :9455-9461

[2] A simple, rapid, and efficient N-Boc protection of amines under ultrasound irradiation and catalyst-free conditions [J].

Amira, Aicha ;

K'tir, Hacene ;

Berredjem, Malika ;

Aouf, Nour-Eddine .

MONATSHEFTE FUR CHEMIE, 2014, 145 (03) :509-515

[3]

Andersen K.K., 1979, COMPREHENSIVE ORGANI, V3

[4] Synthesis and structural study of new substituted chiral sulfamoyl oxazolidin-2-ones [J].

Barbey, Carole ;

Bouasla, Radia ;

Berredjem, Malika ;

Dupont, Nathalie ;

Retailleau, Pascal ;

Aouf, Nour-Eddine ;

Lecouvey, Marc .

TETRAHEDRON, 2012, 68 (44) :9125-9130

[5]

Belghiche R., 2012, Eur. J. Chem, V3, P305, DOI [DOI 10.1016/J.BJP.2015.11.006, DOI 10.5155/EURJCHEM.3.3.305-309.610]

[6]

Berredjem M., 2010, XRAY STRUCTURE ANAL, V26, P14, DOI [10.2116/xraystruct.26.13, DOI 10.2116/xraystruct.26.13, https://doi.org/10.2116/xraystruct.26.13]

[7] 1,2,3,4-Tetrahydroisoquinoline-2-sulfonamide [J].

Bouasla, Radia ;

Berredjem, Malika ;

Aouf, Nour-Eddine ;

Barbey, Carole .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :O432-U2236

[8]

Cheraiet Z., 2012, Int. J. Chem, V4

[9] A simple and eco-sustainable method for the O-Boc protection/deprotection of various phenolic structures under water-mediated/catalyst-free conditions [J].

Cheraiet, Zinelaabidine ;

Hessainia, Sihem ;

Ouarna, Souad ;

Berredjem, Malika ;

Aouf, Nour-Eddine .

GREEN CHEMISTRY LETTERS AND REVIEWS, 2013, 6 (03) :211-216

[10]

Connor E. E., 1998, Primary Care Update for Ob/Gyns, V5, P32, DOI 10.1016/S1068-607X(97)00121-2

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