Application of tris(trimethylsilyl)methyl derivatives in polymer chemistry

被引：1
|
作者：
Kowalewska, A
Stanczyk, W
Eckberg, R
机构：
[1] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland
[2] GE Co, Silicone Prod Div, Waterford, NY 12188 USA
来源：
POLIMERY | 2004年 / 49卷 / 7-8期
关键词：
tris(trimethylsilyl)methyl derivatives; thermal stability; liquid crystalline polymers; curing of polysiloxanes; dendrimers; acid amplifiers;
D O I：
10.14314/polimery.2004.479
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Several directions of application of title derivatives, which because of unusual steric hindrance (Scheme A) show excellent thermal, chemical and hydrolytic stability, were presented. Linear liquid crystalline polymers containing "trisyl" fragments (Scheme B, Table 1) have been discussed as well as the polymers showing dendrimeric structures (Schemes C-E) and modified (cured) polysiloxanes (Fig. 1, Table 2). The syntheses of acid amplifiers (Schemes H-J) used e.g. for curing of polysiloxanes with epoxy side groups were discussed.
引用
收藏
页码：479 / 485
页数：7
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