Application of tris(trimethylsilyl)methyl derivatives in polymer chemistry

被引：1
|
作者：
Kowalewska, A
Stanczyk, W
Eckberg, R
机构：
[1] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland
[2] GE Co, Silicone Prod Div, Waterford, NY 12188 USA
来源：
POLIMERY | 2004年 / 49卷 / 7-8期
关键词：
tris(trimethylsilyl)methyl derivatives; thermal stability; liquid crystalline polymers; curing of polysiloxanes; dendrimers; acid amplifiers;
D O I：
10.14314/polimery.2004.479
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Several directions of application of title derivatives, which because of unusual steric hindrance (Scheme A) show excellent thermal, chemical and hydrolytic stability, were presented. Linear liquid crystalline polymers containing "trisyl" fragments (Scheme B, Table 1) have been discussed as well as the polymers showing dendrimeric structures (Schemes C-E) and modified (cured) polysiloxanes (Fig. 1, Table 2). The syntheses of acid amplifiers (Schemes H-J) used e.g. for curing of polysiloxanes with epoxy side groups were discussed.
引用
收藏
页码：479 / 485
页数：7
相关论文
共 50 条
  • [11] TRIS(TRIMETHYLSILYL)METHYL GERMANIUM HALIDES
    EABORN, C
    SIEW, NPY
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 202 (02) : 157 - 162
  • [12] SYNTHESIS OF BIS(TRIMETHYLSILYL)-METHYL-AMINOFLUOROSILANES AND TRIS(TRIMETHYLSILYL)-METHYL-AMINOFLUOROSILANES
    KLINGEBIEL, U
    SKODA, L
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1984, 510 (03): : 175 - 179
  • [13] Base-free tris(trimethylsilyl)methyl derivatives of lithium, aluminium, gallium, and indium
    Schaller, F
    Schwarz, W
    Hausen, HD
    Klinkhammer, KW
    Weidlein, J
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (09): : 1455 - 1466
  • [14] PREPARATION AND CHEMISTRY OF TRIS(TRIMETHYLSILYL)SILYL AND BIS(MESITYL)SILYL DERIVATIVES OF ZIRCONIUM AND HAFNIUM
    TILLEY, TD
    RODDICK, DM
    CAMPION, BK
    ELSNER, FH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 191 : 389 - INOR
  • [15] OZONOLYSIS OF BIS[TRIS(TRIMETHYLSILYL)METHYL]DIPHOSPHENE
    CAMINADE, AM
    COURET, C
    ESCUDIE, J
    KOENIG, M
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (24) : 1622 - 1623
  • [16] STRUCTURE OF TRIS[BIS(TRIMETHYLSILYL)METHYL]TRIPHOSPHIRANE
    BALDY, A
    ESTIENNE, J
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 : 747 - 749
  • [17] CRYSTAL-STRUCTURES OF (TRIS(TRIMETHYLSILYL)METHYL)POTASSIUM AND (TRIS(DIMETHYLPHENYLSILYL)METHYL)POTASSIUM
    EABORN, C
    HITCHCOCK, PB
    IZOD, K
    JAGGAR, AJ
    SMITH, JD
    ORGANOMETALLICS, 1994, 13 (03) : 753 - 754
  • [18] REACTION CHEMISTRY OF TRIS(TRIMETHYLSILYL)AMINE WITH MONOHALOBORANES
    JANIK, JF
    NARULA, CK
    GULLIVER, EG
    DUESLER, EN
    PAINE, RT
    INORGANIC CHEMISTRY, 1988, 27 (07) : 1222 - 1227
  • [19] TRIS(TRIMETHYLSILYL)-METHYL-ORGANYL-CHLORPHOSPHINES
    ISSLEIB, K
    SCHMIDT, H
    WIRKNER, C
    ZEITSCHRIFT FUR CHEMIE, 1980, 20 (11): : 419 - 419
  • [20] ALKALINE-HYDROLYSIS OF METHYL[TRIS(TRIMETHYLSILYL)METHYL]DICHLOROSTANNANE
    BELSKY, VK
    ZEMLYANSKY, NN
    BORISOVA, IV
    KOLOSOVA, ND
    BELETSKAYA, IP
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 254 (02) : 189 - 192
12345