Poly(ester-amide)s Derived From Adipic Acid, 1,4-Butanediol and β-Alanine: Synthesis and Characterization

被引：7

作者：

Abbes, Marwa ^{[1
]}

Salhi, Slim ^{[1
]}

Lefevre, Lenaig ^{[2
]}

Delaite, Christelle ^{[2
]}

Abid, Souhir ^{[1
]}

El Gharbi, Rachid ^{[1
]}

机构：

[1] Univ Sfax, Fac Sci, Lab Chim Appl HCGP, Sfax 3000, Tunisia

[2] Univ Haute Alsace, Lab Photochim & Ingn Macromol, Mulhouse Cedex, France

来源：

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY | 2015年 / 52卷 / 01期

关键词：

thermal properties; Poly(esteramide); melt polycondensation; beta-alanine; EPSILON-CAPROLACTONE; ANIONIC COPOLYMERS; AMIDE)S; POLYESTERAMIDES; COPOLYESTERAMIDES; POLYMERIZATION; DEGRADABILITY; DEGRADATION; GLYCINE; BIODEGRADATION;

D O I：

10.1080/10601325.2014.976752

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of polyesteramides (PEAs) differing in their amide/ester ratio, within a range of molar composition from 90/10 to 10/90, have been synthesized by a direct melt polycondensation of 1,4-butanediol, adipic acid and beta-alanine. Their structure was fully characterized by FTIR and NMR spectroscopy. The resulting copolymers are amorphous, they are thermally stable to temperatures up to 330 degrees C, and present increasing glass transition temperatures at increasing amide content.

引用

页码：56 / 63

页数：8

共 47 条

[1]

Ali Mohamed A., 2014, EUR POLYM J, V53, P160

[2] Study on the degradability of poly(ester amide)s derived from the α-amino acids glycine, and L-alanine containing a variable amide/ester ratio [J].

Armelin, E ;

Paracuellos, N ;

Rodríguez-Galán, A ;

Puiggalí, J .

POLYMER, 2001, 42 (19) :7923-7932

[3] SYNTHESIS AND PROPERTIES OF BIODEGRADABLE COPOLYESTERAMIDES - NYLON 6,6-EPSILON-CAPROLACTONE COPOLYMERS .1. [J].

ARVANITOYANNIS, I ;

NAKAYAMA, A ;

KAWASAKI, N ;

YAMAMOTO, N .

ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1994, 222 :111-123

[4] Sequential poly(ester amide)s based on glycine, diols, and dicarboxylic acids:: Thermal polyesterification versus interfacial polyamidation.: Characterization of polymers containing stiff units [J].

Asín, L ;

Armelin, E ;

Montané, J ;

Rodríguez-Galán, A ;

Puiggalí, J .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (24) :4283-4293

[5] Polymerization of lactams, 95 -: Part 94 -: Preparation of polyesteramides by the anionic polymerization of ε-caprolactam in the presence of poly(ε-caprolactone) [J].

Bernásková, A ;

Chromcová, D ;

Brozek, J ;

Roda, J .

POLYMER, 2004, 45 (07) :2141-2148

[6] Polyesteramides based on PET and nylon 2,T Part 3. Properties [J].

Bouma, K ;

de Wit, G ;

Lohmeijer, JHGM ;

Gaymans, RJ .

POLYMER, 2000, 41 (11) :3965-3974

[7] Polyamide 6-Polycaprolactone Multiblock Copolymers: Synthesis, Characterization, and Degradation [J].

Cakir, Seda ;

Kierkels, Rene ;

Koning, Cor .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (13) :2823-2833

[8] Structural data on regular poly(ester amide)s derived from even diols, glycine, and terephthalic acid [J].

Casas, MT ;

Gestí, S ;

Puiggalí, J .

CRYSTAL GROWTH & DESIGN, 2005, 5 (03) :1099-1107

[9] Polymerization of lactams.: 99 Preparation of polyesteramides by the anionic copolymerization of ε-caprolactam and ε-caprolactone [J].

Chromcova, Daniela ;

Baslerova, Lucie ;

Roda, Jan ;

Brozek, Jiri .

EUROPEAN POLYMER JOURNAL, 2008, 44 (06) :1733-1742

[10] Biodegradable functional poly(ester amide)s with pendant hydroxyl functional groups: Synthesis, characterization, fabrication and in vitro cellular response [J].

Deng, Mingxiao ;

Wu, Jun ;

Reinhart-King, Cynthia A. ;

Chu, Chih-Chang .

ACTA BIOMATERIALIA, 2011, 7 (04) :1504-1515

← 1 2 3 4 5 →